Ultrastable Surface-Dominated Pseudocapacitive Potassium Storage Enabled by Edge-Enriched N-Doped Porous Carbon Nanosheets.

nitrogen doping porous carbon potassium storage ultrastable cycling

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
26 Oct 2020
Historique:
received: 08 04 2020
pubmed: 14 5 2020
medline: 14 5 2020
entrez: 14 5 2020
Statut: ppublish

Résumé

The development of ultrastable carbon materials for potassium storage poses key limitations caused by the huge volume variation and sluggish kinetics. Nitrogen-enriched porous carbons have recently emerged as promising candidates for this application; however, rational control over nitrogen doping is needed to further suppress the long-term capacity fading. Here we propose a strategy based on pyrolysis-etching of a pyridine-coordinated polymer for deliberate manipulation of edge-nitrogen doping and specific spatial distribution in amorphous high-surface-area carbons; the obtained material shows an edge-nitrogen content of up to 9.34 at %, richer N distribution inside the material, and high surface area of 616 m

Identifiants

pubmed: 32400958
doi: 10.1002/anie.202005118
pmc: PMC7687278
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

19460-19467

Subventions

Organisme : National Natural Science Foundation of China
ID : 51972270, 51702262, 51872240,51911530212, 51672225
Organisme : 111 project
ID : B17020
Organisme : Natural Science Foundation of Shaanxi Province
ID : 2020JZ-07
Organisme : Fundamental Research Funds for the Central Universities
ID : 3102019JC005,3102019ghxm004
Organisme : Research Fund of the State Key Laboratory of Solidification Processing (NPU), China
ID : 2019-QZ-03
Organisme : DFG
ID : A 1698/27-1

Informations de copyright

© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

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Auteurs

Fei Xu (F)

State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, P. R. China.
Inorganic Chemistry, Technische Universität Dresden, Bergstrasse 66, 01062, Dresden, Germany.

Yixuan Zhai (Y)

State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, P. R. China.

En Zhang (E)

Inorganic Chemistry, Technische Universität Dresden, Bergstrasse 66, 01062, Dresden, Germany.

Qianhui Liu (Q)

State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, P. R. China.

Guangshen Jiang (G)

State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, P. R. China.

Xiaosa Xu (X)

State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, P. R. China.

Yuqian Qiu (Y)

State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, P. R. China.

Xiaoming Liu (X)

State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P. R. China.

Hongqiang Wang (H)

State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, P. R. China.

Stefan Kaskel (S)

Inorganic Chemistry, Technische Universität Dresden, Bergstrasse 66, 01062, Dresden, Germany.

Classifications MeSH