Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutanediyl.

diradicaloids low-valent species silicon small ring synthesis

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
24 Aug 2020
Historique:
received: 30 04 2020
pubmed: 15 5 2020
medline: 15 5 2020
entrez: 15 5 2020
Statut: ppublish

Résumé

Main group analogues of cyclobutane-1,3-diyls are fascinating due to their unique reactivity and electronic properties. So far only heteronuclear examples have been isolated. Here we report the isolation and characterization of all-silicon 1,3-cyclobutanediyls as stable closed-shell singlet species from the reversible reactions of cyclotrisilene c-Si

Identifiants

pubmed: 32407571
doi: 10.1002/anie.202006283
pmc: PMC7496386
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

15087-15092

Subventions

Organisme : Deutscher Akademischer Austauschdienst
Organisme : Türkiye Bilimsel ve Teknolojik Araştirma Kurumu
ID : 2214-A

Informations de copyright

© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

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Auteurs

Cem B Yildiz (CB)

Department of Aromatic and Medicinal Plants, Aksaray University, 68100, Aksaray, Turkey.

Kinga I Leszczyńska (KI)

Krupp-Chair of Inorganic and General Chemistry, Saarland University, 66123, Saarbrücken, Germany.

Sandra González-Gallardo (S)

Krupp-Chair of Inorganic and General Chemistry, Saarland University, 66123, Saarbrücken, Germany.

Michael Zimmer (M)

Krupp-Chair of Inorganic and General Chemistry, Saarland University, 66123, Saarbrücken, Germany.

Akin Azizoglu (A)

Department of Chemistry, Faculty of Science and Letters, University of Balıkesir, 10145, Balıkesir, Turkey.

Till Biskup (T)

Chair of Physical Chemistry and Chemical Education, Saarland University, 66123, Saarbrücken, Germany.

Christopher W M Kay (CWM)

Chair of Physical Chemistry and Chemical Education, Saarland University, 66123, Saarbrücken, Germany.
London Centre for Nanotechnology, University College London, 17-19 Gordon Street, London, WC1H 0AH, UK.

Volker Huch (V)

Krupp-Chair of Inorganic and General Chemistry, Saarland University, 66123, Saarbrücken, Germany.

Henry S Rzepa (HS)

Department of Chemistry, Imperial College London, MSRH, White City Campus, 80 Wood Lane, London, W12 0BZ, UK.

David Scheschkewitz (D)

Krupp-Chair of Inorganic and General Chemistry, Saarland University, 66123, Saarbrücken, Germany.

Classifications MeSH