Metal-Free Hydrogen-Bonded Polymers Mimic Noble Metal Electrocatalysts.
conducting polymers
electrocatalysis
hydrogen bonds
hydrogen evolution reaction
polydopamine
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Jun 2020
Jun 2020
Historique:
received:
05
04
2019
revised:
15
04
2020
accepted:
16
04
2020
pubmed:
19
5
2020
medline:
19
5
2020
entrez:
19
5
2020
Statut:
ppublish
Résumé
The most active and efficient catalysts for the electrochemical hydrogen evolution reaction (HER) rely on platinum, a fact that increases the cost of producing hydrogen and thereby limits the widespread adoption of this fuel. Here, a metal-free organic electrocatalyst that mimics the platinum surface by implementing a high work function and incorporating hydrogen-affine hydrogen bonds is introduced. These motifs, inspired from enzymology, are deployed here as selective reaction centres. It is shown that the keto-amine hydrogen-bond motif enhances the rate-determining step in proton reduction to molecular hydrogen. The keto-amine-functionalized polymers reported herein evolve hydrogen at an overpotential of 190 mV. They share certain key properties with platinum: a similar work function and excellent electrochemical stability and chemical robustness. These properties allow the demonstration of one week of continuous HER operation without notable degradation nor delamination from the carrier electrode. Scaled continuous-flow electrolysis is reported and 1 L net molecular hydrogen is produced within less than 9 h using 2.3 mg of polymer electrocatalyst.
Identifiants
pubmed: 32419235
doi: 10.1002/adma.201902177
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e1902177Subventions
Organisme : Austrian Science Fund
ID : FWF I3822 N37
Organisme : Austrian Federal Ministry of Science
Organisme : Research and Economy and the National Foundation for Research, Technology and Development
Organisme : NSERC
Informations de copyright
© 2020 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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