An Ultra-Microporous Metal-Organic Framework with Exceptional Xe Capacity.

MOFs confinement nickel-isonicitinate ultra-micropores xenon capture

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
01 Oct 2020
Historique:
received: 11 05 2020
pubmed: 20 5 2020
medline: 20 5 2020
entrez: 20 5 2020
Statut: ppublish

Résumé

Molecular confinement plays a significant effect on trapped gas and solvent molecules. A fundamental understanding of gas adsorption within the porous confinement provides information necessary to design a material with improved selectivity. In this regard, metal-organic framework (MOF) adsorbents are ideal candidate materials to study confinement effects for weakly interacting gas molecules, such as noble gases. Among the noble gases, xenon (Xe) has practical applications in the medical, automotive and aerospace industries. In this Communication, we report an ultra-microporous nickel-isonicotinate MOF with exceptional Xe uptake and selectivity compared to all benchmark MOF and porous organic cage materials. The selectivity arises because of the near perfect fit of the atomic Xe inside the porous confinement. Notably, at low partial pressure, the Ni-MOF interacts very strongly with Xe compared to the closely related Krypton gas (Kr) and more polarizable CO

Identifiants

pubmed: 32428326
doi: 10.1002/chem.202002331
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

12544-12548

Subventions

Organisme : Defense Threat Reduction Agency
ID : HDTRA-19-31270

Informations de copyright

© 2020 Wiley-VCH GmbH.

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Auteurs

Debanjan Chakraborty (D)

Department of Chemistry and Centre for Energy Science, Indian Institute of Science Education and Research, Pune, Maharashtra, 411008, India.

Shyamapada Nandi (S)

Department of Chemistry and Centre for Energy Science, Indian Institute of Science Education and Research, Pune, Maharashtra, 411008, India.

Rahul Maity (R)

Department of Chemistry and Centre for Energy Science, Indian Institute of Science Education and Research, Pune, Maharashtra, 411008, India.

Radha Kishan Motkuri (RK)

Pacific Northwest National Laboratory, Richland, Washington, 99354, United States.

Kee Sung Han (KS)

Pacific Northwest National Laboratory, Richland, Washington, 99354, United States.

Sean Collins (S)

Centre for Catalysis Research and Innovation, & Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Ontario, K1N 6N5, Canada.

Paul Humble (P)

Pacific Northwest National Laboratory, Richland, Washington, 99354, United States.

James C Hayes (JC)

Pacific Northwest National Laboratory, Richland, Washington, 99354, United States.

Tom K Woo (TK)

Centre for Catalysis Research and Innovation, & Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Ontario, K1N 6N5, Canada.

Ramanathan Vaidhyanathan (R)

Department of Chemistry and Centre for Energy Science, Indian Institute of Science Education and Research, Pune, Maharashtra, 411008, India.

Praveen K Thallapally (PK)

Pacific Northwest National Laboratory, Richland, Washington, 99354, United States.

Classifications MeSH