Pre-Polymerization Enables Controllable Synthesis of Nanosheet-Based Porphyrin Polymers towards High-Performance Li-Ion Batteries.

lithium-ion batteries nanosheets porphyrin polymer pre-polymerization self-assembly

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
17 Aug 2020
Historique:
received: 21 04 2020
pubmed: 20 5 2020
medline: 20 5 2020
entrez: 20 5 2020
Statut: ppublish

Résumé

The precise regulation of nucleation growth and assembly of polymers is still an intriguing goal but an enormous challenge. In this study, we proposed a pre-polymerization strategy to regulate the assembly and growth of polymers by facilely controlling the concentration of polymerization initiator, and thus obtained two kinds of different nanosheet-based porphyrin polymer materials using tetrakis-5,10,15,20-(4-aminophenyl) porphyrin (TAPP) as the precursor. Notably, due to the π-π stacking and doping of TAPP during the preparation process, the obtained PTAPP-nanocube material exhibits a high intrinsic bulk conductivity reaching 1.49×10

Identifiants

pubmed: 32428368
doi: 10.1002/chem.202001943
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

10433-10438

Subventions

Organisme : Natural Science Foundation of China
ID : 51773062
Organisme : Natural Science Foundation of China
ID : 61831021

Informations de copyright

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Zhuolei Han (Z)

State Key Laboratory of Precision Spectroscopy, Engineering Research Center for Nanophotonics and Advanced Instrument (Ministry of Education), School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, P. R. China.

Yan Ai (Y)

State Key Laboratory of Precision Spectroscopy, Engineering Research Center for Nanophotonics and Advanced Instrument (Ministry of Education), School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, P. R. China.

Xiaolin Jiang (X)

State Key Laboratory of Precision Spectroscopy, Engineering Research Center for Nanophotonics and Advanced Instrument (Ministry of Education), School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, P. R. China.

Yuxiu You (Y)

Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.

Facai Wei (F)

State Key Laboratory of Precision Spectroscopy, Engineering Research Center for Nanophotonics and Advanced Instrument (Ministry of Education), School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, P. R. China.

Hao Luo (H)

State Key Laboratory of Precision Spectroscopy, Engineering Research Center for Nanophotonics and Advanced Instrument (Ministry of Education), School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, P. R. China.

Jing Cui (J)

State Key Laboratory of Precision Spectroscopy, Engineering Research Center for Nanophotonics and Advanced Instrument (Ministry of Education), School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, P. R. China.

Qinye Bao (Q)

State Key Laboratory of Precision Spectroscopy, Engineering Research Center for Nanophotonics and Advanced Instrument (Ministry of Education), School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, P. R. China.

Jianwei Fu (J)

School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, 450052, P. R. China.

Qingguo He (Q)

State Key Lab of Transducer Technology, Shanghai Institute of, Microsystem and Information Technology, Chinese Academy of, Sciences, Shanghai, 200050, P.R. China.

Shaohua Liu (S)

State Key Laboratory of Precision Spectroscopy, Engineering Research Center for Nanophotonics and Advanced Instrument (Ministry of Education), School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, P. R. China.
State Key Lab of Transducer Technology, Shanghai Institute of, Microsystem and Information Technology, Chinese Academy of, Sciences, Shanghai, 200050, P.R. China.

Jiangong Cheng (J)

State Key Lab of Transducer Technology, Shanghai Institute of, Microsystem and Information Technology, Chinese Academy of, Sciences, Shanghai, 200050, P.R. China.

Classifications MeSH