Guanidinium-Assisted Surface Matrix Engineering for Highly Efficient Perovskite Quantum Dot Photovoltaics.

CsPbI3 guanidinium thiocyanate ligand exchange perovskite quantum dots solar cells

Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Jul 2020
Historique:
received: 19 03 2020
revised: 23 04 2020
accepted: 29 04 2020
pubmed: 26 5 2020
medline: 26 5 2020
entrez: 26 5 2020
Statut: ppublish

Résumé

Metal halide perovskite quantum dots (Pe-QDs) are of great interest in new-generation photovoltaics (PVs). However, it remains challenging in the construction of conductive and intact Pe-QD films to maximize their functionality. Herein, a ligand-assisted surface matrix strategy to engineer the surface and packing states of Pe-QD solids is demonstrated by a mild thermal annealing treatment after ligand exchange processing (referred to as "LE-TA") triggered by guanidinium thiocyanate. The "LE-TA" method induces the formation of surface matrix on CsPbI

Identifiants

pubmed: 32449221
doi: 10.1002/adma.202001906
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2001906

Subventions

Organisme : National Key Research and Development Program of China
ID : 2016YFA0202402
Organisme : National Key Research and Development Program of China
ID : 2017YFA0205002
Organisme : National Natural Science Foundation of China
ID : 51761145013
Organisme : National Natural Science Foundation of China
ID : 61911530158
Organisme : National Natural Science Foundation of China
ID : 51803144
Organisme : National Natural Science Foundation of China
ID : 61674111
Organisme : Natural Science Foundation of Jiangsu Province
ID : BK20170337
Organisme : 111 Project
Organisme : U.S. Department of Energy
ID : DE-AC36-08GO28308

Informations de copyright

© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Xufeng Ling (X)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Jianyu Yuan (J)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Xuliang Zhang (X)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Yuli Qian (Y)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Shaik M Zakeeruddin (SM)

Laboratory of Photonics and Interfaces (LPI), Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, CH-1015, Switzerland.

Bryon W Larson (BW)

Chemistry & Nanoscience Center, National Renewable Energy Laboratory, Golden, CO, 80401, USA.

Qian Zhao (Q)

Chemistry & Nanoscience Center, National Renewable Energy Laboratory, Golden, CO, 80401, USA.

Junwei Shi (J)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Jiacheng Yang (J)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Kang Ji (K)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Yannan Zhang (Y)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Yongjie Wang (Y)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Chunyang Zhang (C)

Laboratory of Photonics and Interfaces (LPI), Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, CH-1015, Switzerland.

Steffen Duhm (S)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Joseph M Luther (JM)

Chemistry & Nanoscience Center, National Renewable Energy Laboratory, Golden, CO, 80401, USA.

Michael Grätzel (M)

Laboratory of Photonics and Interfaces (LPI), Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, CH-1015, Switzerland.

Wanli Ma (W)

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, P. R. China.

Classifications MeSH