Oxidation, Coordination, and Nickel-Mediated Deconstruction of a Highly Electron-Rich Diboron Analogue of 1,3,5-Hexatriene.
carbenes
conjugation
density-functional calculations
rearrangements
structure elucidation
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
01 Sep 2020
01 Sep 2020
Historique:
received:
28
04
2020
pubmed:
26
5
2020
medline:
26
5
2020
entrez:
26
5
2020
Statut:
ppublish
Résumé
The reductive coupling of an N-heterocyclic carbene (NHC) stabilized (dibromo)vinylborane yields a 1,2-divinyldiborene, which, although isoelectronic to a 1,3,5-triene, displays no extended π conjugation because of twisting of the C
Identifiants
pubmed: 32449598
doi: 10.1002/anie.202006131
pmc: PMC7497145
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
15717-15725Subventions
Organisme : H2020 European Research Council
ID : 669054
Organisme : Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
Organisme : Alexander von Humboldt-Stiftung
Informations de copyright
© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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