Synthesis of Chiral MOF-74 Frameworks by Post-Synthetic Modification by Using an Amino Acid.
chiral induction
chirality
defects
metal-organic frameworks
post-synthetic modifications
vibrational circular dichroism
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
02 Nov 2020
02 Nov 2020
Historique:
received:
08
05
2020
revised:
25
05
2020
pubmed:
28
5
2020
medline:
28
5
2020
entrez:
28
5
2020
Statut:
ppublish
Résumé
The synthesis of chiral metal-organic frameworks (MOFs) is highly relevant for asymmetric heterogenous catalysis, yet very challenging. Chiral MOFs with MOF-74 topology were synthesised by using post-synthetic modification with proline. Vibrational circular dichroism studies demonstrate that proline is the source of chirality. The solvents used in the synthesis play a key role in tuning the loading of proline and its interaction with the MOF-74 framework. In N,N'-dimethylformamide, proline coordinates monodentate to the Zn
Identifiants
pubmed: 32459371
doi: 10.1002/chem.202002293
pmc: PMC7702064
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
13957-13965Subventions
Organisme : Nederlandse Organisatie voor Wetenschappelijk Onderzoek
ID : 718.015.004
Informations de copyright
© 2020 The Authors. Published by Wiley-VCH GmbH.
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