The Impact of Aggregation on the Photophysics of Spiro-Bridged Heterotriangulenes.
aggregation
density functional theory calculations
heteropolycycles
morphology
photophysics
spiro compounds
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
07 Sep 2020
07 Sep 2020
Historique:
received:
07
03
2020
revised:
12
05
2020
pubmed:
31
5
2020
medline:
31
5
2020
entrez:
31
5
2020
Statut:
ppublish
Résumé
We report on the impact of the central heteroatom on structural, electronic, and spectroscopic properties of a series of spirofluorene-bridged heterotriangulenes and provide a detailed study on their aggregates. The in-depth analysis of their molecular structure by NMR spectroscopy and X-ray crystallography was further complemented by density functional theory calculations. With the aid of extensive photophysical analysis the complex fluorescence spectra were deconvoluted showing contributions from the peripheral fluorenes and the heteroaromatic cores. Beyond the molecular scale, we examined the aggregation behavior of these heterotriangulenes in THF/H
Identifiants
pubmed: 32472586
doi: 10.1002/anie.202003504
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
16233-16240Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : 182849149
Organisme : Deutsche Forschungsgemeinschaft
ID : 401247651
Organisme : Deutsche Forschungsgemeinschaft
ID : SFB 1249
Organisme : French National Research Agency
ID : ANR-17-CE05-0005-01
Organisme : French National Research Agency
ID : ANR-10-EQPX-29-01
Organisme : Deutsche Forschungsgemeinschaft
ID : SCHA 2061/2-1
Organisme : Verband der Chemischen Industrie
ID : Liebig Scholarship
Informations de copyright
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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