Metal-Free C-H Borylation of N-Heteroarenes by Boron Trifluoride.

C−H activation boron trifluoride borylation frustrated Lewis pairs protodeboronation

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
02 Nov 2020
Historique:
received: 24 03 2020
revised: 28 05 2020
pubmed: 2 6 2020
medline: 2 6 2020
entrez: 2 6 2020
Statut: ppublish

Résumé

Organoboron compounds are essential reagents in modern C-C coupling reactions. Their synthesis via catalytic C-H borylation by main group elements is emerging as a powerful tool alternative to transition metal based catalysis. Herein, a straightforward metal-free synthesis of aryldifluoroboranes from BF

Identifiants

pubmed: 32478432
doi: 10.1002/chem.202001436
pmc: PMC7702085
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

13873-13879

Subventions

Organisme : Luonnontieteiden ja Tekniikan Tutkimuksen Toimikunta
ID : 316207
Organisme : Nemzeti Kutatási Fejlesztési és Innovációs Hivatal
ID : K-115660

Informations de copyright

© 2020 The Authors. Published by Wiley-VCH GmbH.

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Auteurs

Vladimir Iashin (V)

Department of Chemistry, University of Helsinki, A. I. Virtasen aukio, 1, 00014, Helsinki, Finland.

Dénes Berta (D)

Institute of Organic Chemistry, Research Centre for Natural Sciences, Magyar tudósok körútja 2, 1117, Budapest, Hungary.

Konstantin Chernichenko (K)

Department of Chemistry, University of Helsinki, A. I. Virtasen aukio, 1, 00014, Helsinki, Finland.
Present address: API Small Molecule Development, Janssen Pharmaceutica N.V., Turnhoutseweg 30, 2340, Beerse, Belgium.

Martin Nieger (M)

Department of Chemistry, University of Helsinki, A. I. Virtasen aukio, 1, 00014, Helsinki, Finland.

Karina Moslova (K)

Department of Chemistry, University of Helsinki, A. I. Virtasen aukio, 1, 00014, Helsinki, Finland.

Imre Pápai (I)

Institute of Organic Chemistry, Research Centre for Natural Sciences, Magyar tudósok körútja 2, 1117, Budapest, Hungary.

Timo Repo (T)

Department of Chemistry, University of Helsinki, A. I. Virtasen aukio, 1, 00014, Helsinki, Finland.

Classifications MeSH