Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer.
chromophores
dimers
energy transfer
noncovalent interactions
supramolecular chemistry
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
07 09 2020
07 09 2020
Historique:
received:
05
05
2020
pubmed:
5
6
2020
medline:
5
6
2020
entrez:
5
6
2020
Statut:
ppublish
Résumé
The challenge of quantitatively forming self-assembled heterodimers without other equilibrium by-products is overcome through self-sorting favored by the introduction of designed shape-complementary moieties. Such a supramolecular strategy based on cucurbit[8]uril-directed dimerization is further applied to generate hetero-chromophore dimers quantitatively, leading to efficient energy transfer (>85 %) upon photoexcitation.
Identifiants
pubmed: 32495447
doi: 10.1002/anie.202006530
pmc: PMC7540262
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
15963-15967Informations de copyright
© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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