Phenalenannulations: Three-Point Double Annulation Reactions that Convert Benzenes into Pyrenes.
alkynes
annulation
arenes
pyrenes
radical reactions
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
17 Aug 2020
17 Aug 2020
Historique:
received:
27
04
2020
pubmed:
5
6
2020
medline:
5
6
2020
entrez:
5
6
2020
Statut:
ppublish
Résumé
3-Point annulations, or phenalenannulations, transform a benzene ring directly into a substituted pyrene by "wrapping" two new cycles around the perimeter of the central ring at three consecutive carbon atoms. This efficient, modular, and general method for π-extension opens access to non-symmetric pyrenes and their expanded analogues. Potentially, this approach can convert any aromatic ring bearing a -CH
Identifiants
pubmed: 32495480
doi: 10.1002/anie.202006087
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
14352-14357Subventions
Organisme : National Science Foundation
ID : CHE1800329
Organisme : National Science Foundation
ID : CHE-1828362
Organisme : National Science Foundation
ID : 1752782
Informations de copyright
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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