The Earlier the Better: Structural Analysis and Separation of Lanthanides with Pyrroloquinoline Quinone.
PQQ
coordination chemistry
lanthanides
rare earth elements
separations
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
06 Aug 2020
06 Aug 2020
Historique:
received:
01
06
2020
pubmed:
5
6
2020
medline:
5
6
2020
entrez:
5
6
2020
Statut:
ppublish
Résumé
Lanthanides (Ln) are critical raw materials, however, their mining and purification have a considerable negative environmental impact and sustainable recycling and separation strategies for these elements are needed. In this study, the precipitation and solubility behavior of Ln complexes with pyrroloquinoline quinone (PQQ), the cofactor of recently discovered lanthanide (Ln) dependent methanol dehydrogenase (MDH) enzymes, is presented. In this context, the molecular structure of a biorelevant europium PQQ complex was for the first time elucidated outside a protein environment. The complex crystallizes as an inversion symmetric dimer, Eu
Identifiants
pubmed: 32497263
doi: 10.1002/chem.202002653
pmc: PMC7496819
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
10133-10139Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : 392552271
Informations de copyright
© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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