Using energy balance to determine pore-scale wettability.

Contact angle Energy balance Lattice Boltzmann method Multiphase flow Porous media Surface energy Thermodynamic contact angle Viscous dissipation Wettability

Journal

Journal of colloid and interface science
ISSN: 1095-7103
Titre abrégé: J Colloid Interface Sci
Pays: United States
ID NLM: 0043125

Informations de publication

Date de publication:
15 Sep 2020
Historique:
received: 13 02 2020
revised: 19 03 2020
accepted: 20 03 2020
pubmed: 6 6 2020
medline: 6 6 2020
entrez: 6 6 2020
Statut: ppublish

Résumé

Based on energy balance during two-phase displacement in porous media, it has recently been shown that a thermodynamically consistent contact angle can be determined from micro-tomography images. However, the impact of viscous dissipation on the energy balance has not been fully understood. Furthermore, it is of great importance to determine the spatial distribution of wettability. We use direct numerical simulation to validate the determination of the thermodynamic contact angle both in an entire domain and on a pore-by-pore basis. Two-phase direct numerical simulations are performed on complex 3D porous media with three wettability states: uniformly water-wet, uniformly oil-wet, and non-uniform mixed-wet. Using the simulated fluid configurations, the thermodynamic contact angle is computed, then compared with the input contact angles. The impact of viscous dissipation on the energy balance is quantified; it is insignificant for water flooding in water-wet and mixed-wet media, resulting in an accurate estimation of a representative contact angle for the entire domain even if viscous effects are ignored. An increasing trend in the computed thermodynamic contact angle during water injection is shown to be a manifestation of the displacement sequence. Furthermore, the spatial distribution of wettability can be represented by the thermodynamic contact angle computed on a pore-by-pore basis.

Identifiants

pubmed: 32502883
pii: S0021-9797(20)30372-6
doi: 10.1016/j.jcis.2020.03.074
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

486-495

Informations de copyright

Copyright © 2020 The Author(s). Published by Elsevier Inc. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Takashi Akai (T)

Department of Earth Science and Engineering, Imperial College London, SW7 2BP, UK. Electronic address: t.akai17@imperial.ac.uk.

Qingyang Lin (Q)

Department of Earth Science and Engineering, Imperial College London, SW7 2BP, UK.

Branko Bijeljic (B)

Department of Earth Science and Engineering, Imperial College London, SW7 2BP, UK.

Martin J Blunt (MJ)

Department of Earth Science and Engineering, Imperial College London, SW7 2BP, UK.

Classifications MeSH