Preparation of carbon-coated brookite@anatase TiO


Journal

Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
ISSN: 1474-9092
Titre abrégé: Photochem Photobiol Sci
Pays: England
ID NLM: 101124451

Informations de publication

Date de publication:
15 Jul 2020
Historique:
pubmed: 12 6 2020
medline: 12 6 2020
entrez: 12 6 2020
Statut: ppublish

Résumé

One-dimensional TiO2@C nanocables with a heterophase junction have been successfully prepared by coating brookite@anatase TiO2 with a thin layer of hydrothermal carbon (HTC). Compared with anatase TiO2, the biphase brookite@anatase structure can reduce the recombination rate of the excited electron/hole pairs of TiO2. The HTC coating not only enhances the adsorption capability of the TiO2 catalyst for organic pollutants but also facilitates photogenerated electron transfer to further increase its photocatalytic activity. Therefore, compared with anatase TiO2, brookite@anatase TiO2, and TiO2@C, the brookite@anatase TiO2@C shows the highest photocatalytic activity for the photodegradation of tetracycline (TC) under the irradiation of UV-visible light. Moreover, ˙O2 has been proved to be the predominant active species for the photodegradation of TC, and the photocatalytic mechanism of brookite@anatase TiO2@C nanocables has also been proposed.

Identifiants

pubmed: 32525187
doi: 10.1039/d0pp00004c
pii: 10.1039/d0pp00004c
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

966-975

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Auteurs

Rui Tan (R)

State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Key Laboratory of Green Chemical Technology and Process Engineering, School of Chemistry and Chemical Engineering, Tiangong University, 300387, Tianjin, China.

Yonglin Wang (Y)

State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Key Laboratory of Green Chemical Technology and Process Engineering, School of Chemistry and Chemical Engineering, Tiangong University, 300387, Tianjin, China.

Zhouzheng Jin (Z)

State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Key Laboratory of Green Chemical Technology and Process Engineering, School of Chemistry and Chemical Engineering, Tiangong University, 300387, Tianjin, China.

Peng Zhang (P)

State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Key Laboratory of Green Chemical Technology and Process Engineering, School of Chemistry and Chemical Engineering, Tiangong University, 300387, Tianjin, China.

Hengzhi Luo (H)

Fushun YiKeSi New Materials Co., Ltd, 113000, Fushun, Liaoning, China.

Dan Liu (D)

State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Key Laboratory of Green Chemical Technology and Process Engineering, School of Chemistry and Chemical Engineering, Tiangong University, 300387, Tianjin, China. liudan@tjpu.edu.cn.
College of Science, Engineering and Technology, University of South Africa, Nanotechnology and Water Sustainability Research Unit, Florida Science Campus 1710, South Africa. liudan@tjpu.edu.cn.

Bhekie B Mamba (BB)

College of Science, Engineering and Technology, University of South Africa, Nanotechnology and Water Sustainability Research Unit, Florida Science Campus 1710, South Africa.

Alex T Kuvarega (AT)

College of Science, Engineering and Technology, University of South Africa, Nanotechnology and Water Sustainability Research Unit, Florida Science Campus 1710, South Africa.

Jianzhou Gui (J)

State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Key Laboratory of Green Chemical Technology and Process Engineering, School of Chemistry and Chemical Engineering, Tiangong University, 300387, Tianjin, China.
College of Science, Engineering and Technology, University of South Africa, Nanotechnology and Water Sustainability Research Unit, Florida Science Campus 1710, South Africa.

Classifications MeSH