anion coordination
functionalised imidazoles
ligands
nanoparticles
sensing applications
Journal
ChemistryOpen
ISSN: 2191-1363
Titre abrégé: ChemistryOpen
Pays: Germany
ID NLM: 101594811
Informations de publication
Date de publication:
06 2020
06 2020
Historique:
received:
14
05
2020
revised:
18
05
2020
entrez:
13
6
2020
pubmed:
13
6
2020
medline:
13
6
2020
Statut:
epublish
Résumé
Metal nanoparticles (NPs) have physicochemical properties which are distinct from both the bulk and molecular metal species, and provide opportunities in fields such as catalysis and sensing. NPs typically require protection of their surface to impede aggregation, but these coatings can also block access to the surface which would be required to take advantage of their unusual properties. Here, we show that alkyl imidazoles can stabilise Pd, Pt, Au, and Ag NPs, and delineate the limits of their synthesis. These ligands provide an intermediate level of surface protection, for which we demonstrate proof-of-principle in catalysis and anion binding.
Identifiants
pubmed: 32528790
doi: 10.1002/open.202000145
pii: OPEN202000145
pmc: PMC7280736
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Pagination
683-690Informations de copyright
© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
Déclaration de conflit d'intérêts
The authors declare no conflict of interest.
Références
Chemistry. 2007;13(1):32-9
pubmed: 17115465
J Hazard Mater. 2005 Aug 31;123(1-3):232-41
pubmed: 15936875
Langmuir. 2008 Apr 1;24(7):3471-8
pubmed: 18278970
J Am Chem Soc. 2004 Jun 30;126(25):7780-1
pubmed: 15212517
Environ Sci Technol. 2013 Jun 4;47(11):5738-45
pubmed: 23641814
Beilstein J Nanotechnol. 2017 Dec 7;8:2625-2639
pubmed: 29259877
Chem Commun (Camb). 2013 Mar 21;49(23):2293-5
pubmed: 23407752
Chem Commun (Camb). 2009 Jun 14;(22):3258-60
pubmed: 19587932
Chem Rev. 2019 Apr 24;119(8):4986-5056
pubmed: 30938514
Int J Biol Macromol. 2018 Nov;119:505-516
pubmed: 30059736
Carbohydr Polym. 2016 Oct 20;151:649-655
pubmed: 27474610
J Biomed Mater Res A. 2015 Apr;103(4):1436-46
pubmed: 25046830
Small. 2015 Nov 18;11(43):5728-39
pubmed: 26395565
Langmuir. 2010 Jun 15;26(12):10165-70
pubmed: 20373783
J Nanosci Nanotechnol. 2019 Jun 1;19(6):3583-3590
pubmed: 30744789
Chem Commun (Camb). 2009 Feb 21;(7):812-4
pubmed: 19322450
Inorg Chem. 2014 Nov 3;53(21):11802-8
pubmed: 25363304
Nat Chem. 2011 Jun;3(6):478-83
pubmed: 21602864
J Am Chem Soc. 2002 May 22;124(20):5796-810
pubmed: 12010055
J Am Chem Soc. 2007 Mar 7;129(9):2418-9
pubmed: 17286405