Cooperative Conical Intersection Dynamics of Two Pyrazine Molecules in an Optical Cavity.

Hybrid light-matter states in optical cavities, known as polaritons, offer a novel means of manipulating and controlling photochemical processes. We investigate the cooperative cavity photochemistry of two pyrazine molecules undergoing conical intersection dynamics and interacting with a single cavity photon mode by exact quantum dynamics. When the cavity mode is coupled to the electronic transition between the ground and excited states, we find an enhanced polaritonic splitting and collective dark states. These features dominate the cooperative polariton dynamics and can be observed in the transient absorption spectrum.