Necroptosis Induced by Ruthenium(II) Complexes as Dual Catalytic Inhibitors of Topoisomerase I/II.


Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
14 09 2020
Historique:
received: 27 04 2020
revised: 10 06 2020
pubmed: 14 6 2020
medline: 19 3 2021
entrez: 14 6 2020
Statut: ppublish

Résumé

Inducing necroptosis in cancer cells is an effective approach to circumvent drug-resistance. Metal-based triggers have, however, rarely been reported. Ruthenium(II) complexes containing 1,1-(pyrazin-2-yl)pyreno[4,5-e][1,2,4]triazine were developed with a series of different ancillary ligands (Ru1-7). The combination of the main ligand with bipyridyl and phenylpyridyl ligands endows Ru7 with superior nucleus-targeting properties. As a rare dual catalytic inhibitor, Ru7 effectively inhibits the endogenous activities of topoisomerase (topo) I and II and kills cancer cells by necroptosis. The cell signaling pathway from topo inhibition to necroptosis was elucidated. Furthermore, Ru7 displays significant antitumor activity against drug-resistant cancer cells in vivo. To the best of our knowledge, Ru7 is the first Ru-based necroptosis-inducing chemotherapeutic agent.

Identifiants

pubmed: 32533618
doi: 10.1002/anie.202006089
doi:

Substances chimiques

Coordination Complexes 0
Poly-ADP-Ribose Binding Proteins 0
Topoisomerase Inhibitors 0
Ruthenium 7UI0TKC3U5
DNA Topoisomerases, Type I EC 5.99.1.2
TOP1 protein, human EC 5.99.1.2
DNA Topoisomerases, Type II EC 5.99.1.3
TOP2A protein, human EC 5.99.1.3

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

16631-16637

Informations de copyright

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Deposition Numbers 1941708 (for Ru1), 1941709 (for Ru2), 1941706 (for Ru3), 1941707 (for Ru5), and 1941705 (for Ru6) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service www.ccdc.cam.ac.uk/structures.

Auteurs

Kai Xiong (K)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.

Chen Qian (C)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.

Yixian Yuan (Y)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.

Lin Wei (L)

College of Chemistry, Central China Normal University, Wuhan, 430079, P. R. China.

Xinxing Liao (X)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.

Liting He (L)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.

Thomas W Rees (TW)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.

Yu Chen (Y)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.

Jian Wan (J)

College of Chemistry, Central China Normal University, Wuhan, 430079, P. R. China.

Liangnian Ji (L)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.

Hui Chao (H)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.
College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, 518071, P. R. China.

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