Luminescent ionic liquid formed from a melted rhenium(v) cluster.

Journal

Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838

Informations de publication

Date de publication:
17 Jul 2020
Historique:
pubmed: 17 6 2020
medline: 17 6 2020
entrez: 16 6 2020
Statut: ppublish

Résumé

Recently, non-crystalline coordination materials have been shown to represent a versatile class of functional materials. However, such materials incorporating metal complex clusters have remained largely unexplored. Herein, we demonstrate that a luminescent tetranuclear ReV cluster melts at 489 K, with the cluster structure being maintained in the corresponding supercooled ionic liquid phase.

Identifiants

DOI: 10.1039/d0cc02937h PMID: 32537623
pubmed: 32537623
doi: 10.1039/d0cc02937h
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

7957-7960

Auteurs

Junichi Yanagisawa (J)

Department of Chemistry, Graduate School of Science and Technology Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan. hayami@kumamoto-u.ac.jp.

Tomoaki Hiraoka (T)

Department of Chemistry, Graduate School of Science and Technology Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan. hayami@kumamoto-u.ac.jp.

Fumiya Kobayashi (F)

Department of Chemistry, Graduate School of Science and Technology Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan. hayami@kumamoto-u.ac.jp.
ORCID: 0000-0002-6923-6332

Daisuke Saito (D)

Department of Chemistry, Faculty of Science, Hokkaido University, North-10 West-8, Kita-ku, Sapporo, Hokkaido 060-0810, Japan.
ORCID: 0000-0003-3012-1607

Masaki Yoshida (M)

Department of Chemistry, Faculty of Science, Hokkaido University, North-10 West-8, Kita-ku, Sapporo, Hokkaido 060-0810, Japan.
ORCID: 0000-0002-4744-2805

Masako Kato (M)

Department of Chemistry, Faculty of Science, Hokkaido University, North-10 West-8, Kita-ku, Sapporo, Hokkaido 060-0810, Japan.
ORCID: 0000-0002-6932-9758

Fumitaka Takeiri (F)

Department of Materials Molecular Science, Institute for Molecular Science, 38 Nishigonaka, Myodaiji, Okazaki, Aichi 444-8585, Japan and SOKENDAI (The Graduate University for Advanced Studies), 38 Nishigonaka, Myodaiji, Okazaki, Aichi 444-8585, Japan.
ORCID: 0000-0001-9839-5669

Genki Kobayashi (G)

Department of Materials Molecular Science, Institute for Molecular Science, 38 Nishigonaka, Myodaiji, Okazaki, Aichi 444-8585, Japan and SOKENDAI (The Graduate University for Advanced Studies), 38 Nishigonaka, Myodaiji, Okazaki, Aichi 444-8585, Japan.
ORCID: 0000-0001-6528-0355

Masaaki Ohba (M)

Department of Chemistry, Faculty of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. ohtani@chem.kyushu-univ.jp.
ORCID: 0000-0001-9268-3512

Leonard F Lindoy (LF)

School of Chemistry, The University of Sydney, NSW 2006, Australia.
ORCID: 0000-0003-2409-6935

Ryo Ohtani (R)

Department of Chemistry, Faculty of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan. ohtani@chem.kyushu-univ.jp.
ORCID: 0000-0003-4840-3338

Shinya Hayami (S)

Department of Chemistry, Graduate School of Science and Technology Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan. hayami@kumamoto-u.ac.jp.
ORCID: 0000-0001-8392-2382

Classifications MeSH