The checkerboard model for the eddy-dispersion in laminar flows through porous media. Part I: Theory and velocity field properties.

Band broadening Column technology Eddy-dispersion Modelling Packed bed

Journal

Journal of chromatography. A
ISSN: 1873-3778
Titre abrégé: J Chromatogr A
Pays: Netherlands
ID NLM: 9318488

Informations de publication

Date de publication:
02 Aug 2020
Historique:
received: 17 03 2020
revised: 30 04 2020
accepted: 01 05 2020
entrez: 17 6 2020
pubmed: 17 6 2020
medline: 14 8 2020
Statut: ppublish

Résumé

The additivity assumption underlying Giddings' coupling model for the eddy-dispersion in laminar flows through heterogeneous media is critically analyzed and a potential solution for its non-additivity in the high velocity limit is presented. Whereas the unit cell in Giddings' model only consists of a single velocity bias step, the unit dispersion cell of the newly proposed model comprises two consecutive velocity bias steps. Consequently, the unit cell of this new model allows to account for the occurrence of an internal velocity bias rectification at high reduced velocities and is therefore additive in both the low and high velocity limit. First, a mathematical expression for the velocity- and diffusion-dependency of the model's dispersion characteristics has been established. Subsequently, the physical behavior of the model is discussed. It is shown the relation between the eddy-dispersion plate height h and the reduced velocity ν can be expected to display a local maximum in systems where the transversal dispersion purely occurs by molecular diffusion, as is the case in perfectly ordered flow-through media. In disordered media, where the transversal dispersion also contains a significant advective component, the model predicts a velocity-dependency that is qualitatively similar to that described by Giddings' coupling model but, all other conditions being equal, converges to a significantly smaller horizontal asymptote at high reduced velocity. The latter might shed new light on earlier eddy-dispersion studies pursuing a quantitative agreement between experimental data and the Giddings model.

Identifiants

pubmed: 32540062
pii: S0021-9673(20)30459-3
doi: 10.1016/j.chroma.2020.461195
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

461195

Informations de copyright

Copyright © 2020 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Gert Desmet (G)

Department of Chemical Engineering, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels, Belgium. Electronic address: gedesmet@vub.ac.be.

Bram Huygens (B)

Department of Chemical Engineering, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels, Belgium.

Wim Smits (W)

Department of Chemical Engineering, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels, Belgium.

Sander Deridder (S)

Department of Chemical Engineering, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels, Belgium.

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Classifications MeSH