Simultaneous Determination of Chlorinated and Brominated Acetic Acids in Various Environmental Water Matrixes by High-Performance Liquid Chromatography-Inductively Coupled Plasma Tandem Mass Spectrometry without Sample Preparation.


Journal

Analytical chemistry
ISSN: 1520-6882
Titre abrégé: Anal Chem
Pays: United States
ID NLM: 0370536

Informations de publication

Date de publication:
07 07 2020
Historique:
pubmed: 18 6 2020
medline: 12 2 2021
entrez: 18 6 2020
Statut: ppublish

Résumé

The halogenated acetic acids (HAAs) are generally considered as environmental contaminants and are suspected to pose a major public health concern. The inductively coupled plasma mass spectrometry (ICPMS) has been improved by coupling with the tandem mass spectrometry technology (ICPMS/MS), enabling ultratrace determination of heteroatoms. There have been few reports about the determination of chlorine-containing analytes by high-performance liquid chromatography (HPLC)-ICPMS/MS but none about utilizing this technique for the speciation analysis of organic halogenated compounds in environmental matrixes. We report a rapid method for the simultaneous determination of up to nine chlorinated and brominated acetic acids by HPLC-ICPMS/MS in Austrian surface, ground, and tap water. The chromatographic separation of the main five regulated haloacetic acids (so-called HAA5: chloroacetic acid, dichloroacetic acid, trichloroacetic acid, bromoacetic acid, and dibromoacetic acid) could be achieved in <6 min with limits of detection of 1.4-1.6 μg Cl L

Identifiants

pubmed: 32545952
doi: 10.1021/acs.analchem.0c01456
pmc: PMC7467423
doi:

Substances chimiques

Acetates 0
chloroacetic acid 5GD84Y125G
bromoacetate 68-10-0
dibromoacetic acid 7FUW62YY5L

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

9156-9163

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Auteurs

Bassam Lajin (B)

Institute of Chemistry-Analytical Chemistry for Health and Environment, University of Graz, Universitaetsplatz 1, 8010 Graz, Austria.

Walter Goessler (W)

Institute of Chemistry-Analytical Chemistry for Health and Environment, University of Graz, Universitaetsplatz 1, 8010 Graz, Austria.

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Classifications MeSH