Structural Heterogeneity in Single Particle Imaging Using X-ray Lasers.


Journal

The journal of physical chemistry letters
ISSN: 1948-7185
Titre abrégé: J Phys Chem Lett
Pays: United States
ID NLM: 101526034

Informations de publication

Date de publication:
06 Aug 2020
Historique:
pubmed: 25 6 2020
medline: 20 4 2021
entrez: 25 6 2020
Statut: ppublish

Résumé

One of the challenges facing single particle imaging with ultrafast X-ray pulses is the structural heterogeneity of the sample to be imaged. For the method to succeed with weakly scattering samples, the diffracted images from a large number of individual proteins need to be averaged. The more the individual proteins differ in structure, the lower the achievable resolution in the final reconstructed image. We use molecular dynamics to simulate two globular proteins in vacuum, fully desolvated as well as with two different solvation layers, at various temperatures. We calculate the diffraction patterns based on the simulations and evaluate the noise in the averaged patterns arising from the structural differences and the surrounding water. Our simulations show that the presence of a minimal water coverage with an average 3 Å thickness will stabilize the protein, reducing the noise associated with structural heterogeneity, whereas additional water will generate more background noise.

Identifiants

pubmed: 32578996
doi: 10.1021/acs.jpclett.0c01144
pmc: PMC7416308
doi:

Substances chimiques

Ubiquitin 0
Muramidase EC 3.2.1.17

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

6077-6083

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Auteurs

Thomas Mandl (T)

Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala, Sweden.
University of Applied Sciences Technikum Wien, Höchstädtplatz 6, A-1200 Wien, Austria.

Christofer Östlin (C)

Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala, Sweden.

Ibrahim E Dawod (IE)

Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala, Sweden.
European XFEL GmbH, Holzkoppel 4, DE-22869 Schenefeld, Germany.

Maxim N Brodmerkel (MN)

Department of Chemistry-BMC, Uppsala University, Box 576, SE-751 23 Uppsala, Sweden.

Erik G Marklund (EG)

Department of Chemistry-BMC, Uppsala University, Box 576, SE-751 23 Uppsala, Sweden.

Andrew V Martin (AV)

School of Science, RMIT University, Melbourne, Victoria 3000, Australia.
ARC Centre of Excellence for Advanced Molecular Imaging, Clayton, Victoria 3800, Australia.

Nicusor Timneanu (N)

Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala, Sweden.

Carl Caleman (C)

Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala, Sweden.
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron, Notkestraße 85, DE-22607 Hamburg, Germany.

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Classifications MeSH