Metal-Assisted and Solvent-Mediated Synthesis of Two-Dimensional Triazine Structures on Gram Scale.


Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
29 07 2020
Historique:
pubmed: 1 7 2020
medline: 1 7 2020
entrez: 30 6 2020
Statut: ppublish

Résumé

Covalent triazine frameworks are an emerging material class that have shown promising performance for a range of applications. In this work, we report on a metal-assisted and solvent-mediated reaction between calcium carbide and cyanuric chloride, as cheap and commercially available precursors, to synthesize two-dimensional triazine structures (2DTSs). The reaction between the solvent, dimethylformamide, and cyanuric chloride was promoted by calcium carbide and resulted in dimethylamino-

Identifiants

pubmed: 32597176
doi: 10.1021/jacs.0c02399
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

12976-12986

Auteurs

Abbas Faghani (A)

Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, Berlin 14195, Germany.

Mohammad Fardin Gholami (MF)

Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstr. 15, 12489 Berlin Germany.

Matthias Trunk (M)

Department of Chemistry/Functional Materials, Technische Universität Berlin, Hardenbergstraße 40, 10623 Berlin, Germany.

Johannes Müller (J)

Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstr. 15, 12489 Berlin Germany.

Pradip Pachfule (P)

Department of Chemistry/Functional Materials, Technische Universität Berlin, Hardenbergstraße 40, 10623 Berlin, Germany.

Sarah Vogl (S)

Department of Chemistry/Functional Materials, Technische Universität Berlin, Hardenbergstraße 40, 10623 Berlin, Germany.

Ievgen Donskyi (I)

Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, Berlin 14195, Germany.
BAM-Federal Institute for Material Science and Testing, Division of Surface Analysis and Interfacial Chemistry, Unter den Eichen 44-46, 12205 Berlin, Germany.

Mingjun Li (M)

Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, Berlin 14195, Germany.
Center for Health Science and Engineering, Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, People's Republic of China.

Philip Nickl (P)

Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, Berlin 14195, Germany.
BAM-Federal Institute for Material Science and Testing, Division of Surface Analysis and Interfacial Chemistry, Unter den Eichen 44-46, 12205 Berlin, Germany.

Jingjing Shao (J)

Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, Berlin 14195, Germany.

Michael R S Huang (MRS)

Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstr. 15, 12489 Berlin Germany.

Wolfgang E S Unger (WES)

BAM-Federal Institute for Material Science and Testing, Division of Surface Analysis and Interfacial Chemistry, Unter den Eichen 44-46, 12205 Berlin, Germany.

Raul Arenal (R)

Laboratorio de Microscopias Avanzadas (LMA), Instituto de Nanociencia de Aragon, Universidad de Zaragoza, 50018 Zaragoza, Spain.
Fundacion ARAID, 50018 Zaragoza, Spain.
Instituto de Ciencias de Materiales de Aragon, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain.

Christoph T Koch (CT)

Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstr. 15, 12489 Berlin Germany.

Beate Paulus (B)

Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, Berlin 14195, Germany.

Jürgen P Rabe (JP)

Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstr. 15, 12489 Berlin Germany.

Arne Thomas (A)

Department of Chemistry/Functional Materials, Technische Universität Berlin, Hardenbergstraße 40, 10623 Berlin, Germany.

Rainer Haag (R)

Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, Berlin 14195, Germany.

Mohsen Adeli (M)

Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, Berlin 14195, Germany.
Faculty of Science, Department of Chemistry, Lorestan University, Khorramabad, Iran.

Classifications MeSH