Stretchable and Robust Candle-Soot Nanoparticle-Polydimethylsiloxane Composite Films for Laser-Ultrasound Transmitters.

Considerable attention has been devoted to the development of nanomaterial-based photoacoustic transmitters for ultrasound therapy and diagnosis applications. Here, we fabricate and characterize candle-soot nanoparticles (CSNPs) and polydimethylsiloxane (PDMS) composite-based photoacoustic transmitters, based on a solution process, not just to achieve high-frequency and high-amplitude pressure outputs, but also to develop physically stretchable ultrasound transmitters. Owing to its non-porous and non-agglomerative characteristics, the composite exhibits unique photo-thermal and mechanical properties. The output pressure amplitudes from CSNPs-PDMS composites were 20-26 dB stronger than those of Cr film, used as a reference. The proposed transmitters also offered a center frequency of 2.44-13.34 MHz and 6-dB bandwidths of 5.80-13.62 MHz. Importantly, we characterize the mechanical robustness of CSNPs-PDMS quantitatively, by measuring laser-damage thresholds, to evaluate the upper limit of laser energy that can be ultimately used as an input, i.e., proportional to the maximum-available pressure output. The transmitters could endure an input laser fluence of 54.3-108.6 mJ·cm