Covalent Organic Frameworks for Heterogeneous Catalysis: Principle, Current Status, and Challenges.
Journal
ACS central science
ISSN: 2374-7943
Titre abrégé: ACS Cent Sci
Pays: United States
ID NLM: 101660035
Informations de publication
Date de publication:
24 Jun 2020
24 Jun 2020
Historique:
received:
17
04
2020
entrez:
2
7
2020
pubmed:
2
7
2020
medline:
2
7
2020
Statut:
ppublish
Résumé
Heterogeneous catalysts offer a cyclable platform for exploring efficient transformation systems, and their promising applications underpin a broad research interest. Covalent organic frameworks (COFs) are a class of crystalline porous networks that can integrate organic units into ordered skeletons and pores, offering an insoluble and robust platform for exploring heterogeneous catalysts. In this Outlook, we describe a conceptual scheme for designing catalytic COFs to promote various transformations. We summarize the general strategy for designing COFs to construct tailor-made skeletons and pores by emphasizing their structural uniqueness. We introduce different approaches to develop catalytic functions by sampling COFs into four regimes, i.e., skeletons, walls, pores, and systematically organized systems. We scrutinize their catalytic features and elucidate interplays with electrons, holes, and molecules by highlighting the key role of interface design in exploring catalytic COFs. We further envisage the key issues to be challenged, future research directions, and perspectives to show a full picture of designer heterogeneous catalysis based on COFs.
Identifiants
pubmed: 32607434
doi: 10.1021/acscentsci.0c00463
pmc: PMC7318070
doi:
Types de publication
Journal Article
Review
Langues
eng
Pagination
869-879Informations de copyright
Copyright © 2020 American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.
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