C-H/C-C Functionalization Approach to N-Fused Heterocycles from Saturated Azacycles.


Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
29 07 2020
Historique:
pubmed: 7 7 2020
medline: 16 4 2021
entrez: 7 7 2020
Statut: ppublish

Résumé

Herein we report the synthesis of substituted indolizidines and related N-fused bicycles from simple saturated cyclic amines through sequential C-H and C-C bond functionalizations. Inspired by the Norrish-Yang Type II reaction, C-H functionalization of azacycles is achieved by forming α-hydroxy-β-lactams from precursor α-ketoamide derivatives under mild, visible light conditions. Selective cleavage of the distal C(sp

Identifiants

pubmed: 32627545
doi: 10.1021/jacs.0c04278
pmc: PMC7773224
mid: NIHMS1656304
doi:

Substances chimiques

Aza Compounds 0
Heterocyclic Compounds 0
Indolizidines 0

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

13041-13050

Subventions

Organisme : NIH HHS
ID : S10 OD024998
Pays : United States

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Auteurs

Jin Su Ham (JS)

Department of Chemistry, University of California, Berkeley, California 94720, United States.

Bohyun Park (B)

Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea.
Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea.

Mina Son (M)

Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea.
Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea.

Jose B Roque (JB)

Department of Chemistry, University of California, Berkeley, California 94720, United States.

Justin Jurczyk (J)

Department of Chemistry, University of California, Berkeley, California 94720, United States.

Charles S Yeung (CS)

Disruptive Chemistry Fellow, Department of Discovery Chemistry, Merck & Co., Inc., 33 Avenue Louis Pasteur, Boston, Massachusetts 02115, United States.

Mu-Hyun Baik (MH)

Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea.
Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea.

Richmond Sarpong (R)

Department of Chemistry, University of California, Berkeley, California 94720, United States.

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