Fast motion of molecular rotors in metal-organic framework struts at very low temperatures.
Journal
Nature chemistry
ISSN: 1755-4349
Titre abrégé: Nat Chem
Pays: England
ID NLM: 101499734
Informations de publication
Date de publication:
09 2020
09 2020
Historique:
received:
05
08
2019
accepted:
27
05
2020
pubmed:
8
7
2020
medline:
8
7
2020
entrez:
8
7
2020
Statut:
ppublish
Résumé
The solid state is typically not well suited to sustaining fast molecular motion, but in recent years a variety of molecular machines, switches and rotors have been successfully engineered within porous crystals and on surfaces. Here we show a fast-rotating molecular rotor within the bicyclopentane-dicarboxylate struts of a zinc-based metal-organic framework-the carboxylate groups anchored to the metal clusters act as an axle while the bicyclic unit is free to rotate. The three-fold bipyramidal symmetry of the rotator conflicts with the four-fold symmetry of the struts within the cubic crystal cell of the zinc metal-organic framework. This frustrates the formation of stable conformations, allowing for the continuous, unidirectional, hyperfast rotation of the bicyclic units with an energy barrier of 6.2 cal mol
Identifiants
pubmed: 32632187
doi: 10.1038/s41557-020-0495-3
pii: 10.1038/s41557-020-0495-3
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
845-851Références
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