A large dinuclear Fe(ii) triple helicate demonstrating a two-step spin crossover.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
04 Aug 2020
04 Aug 2020
Historique:
pubmed:
8
7
2020
medline:
8
7
2020
entrez:
8
7
2020
Statut:
ppublish
Résumé
Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe(ii) triple helicate system to exhibit spin crossover-and also a rare example of a 273° helical twist using aromatic spacers-is presented, with exploration of the two-step spin-transition observed.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM