Optimization of Insecticidal Triterpene Derivatives by Biomimetic Oxidations with Hydrogen Peroxide and Iodosobenzene Catalyzed by Mn
Animals
Biomimetic Materials
/ chemical synthesis
Catalysis
Dose-Response Relationship, Drug
Feeding Behavior
/ drug effects
Ferric Compounds
/ chemistry
Hydrogen Peroxide
/ chemistry
Insecta
/ drug effects
Insecticides
/ chemical synthesis
Iodobenzenes
/ chemistry
Manganese
/ chemistry
Metalloporphyrins
/ chemistry
Molecular Structure
Oxidation-Reduction
Structure-Activity Relationship
Triterpenes
/ chemical synthesis
31-norlanostenol
insecticidal effects
metalloporphyrin
oxidation
triterpenoids
Journal
Chemistry & biodiversity
ISSN: 1612-1880
Titre abrégé: Chem Biodivers
Pays: Switzerland
ID NLM: 101197449
Informations de publication
Date de publication:
Sep 2020
Sep 2020
Historique:
received:
13
04
2020
pubmed:
10
7
2020
medline:
30
4
2021
entrez:
10
7
2020
Statut:
ppublish
Résumé
Semisynthetic functionalized triterpenes (4α,14-dimethyl-5α,8α-8,9-epoxycholestan-3β-yl acetate; 4α,14-dimethyl-5α-cholest-8-ene-3,7,11-trione; 4α,14-dimethyl-5α-cholesta-7,9(11)-dien-3-one and 4α,14-dimethyl-5α-cholest-8-en-3β-yl acetate), previously prepared from 31-norlanostenol, a natural insecticide isolated from the latex of Euphorbia officinarum, have been subjected to oxidation with hydrogen peroxide (H
Identifiants
pubmed: 32644248
doi: 10.1002/cbdv.202000287
doi:
Substances chimiques
Ferric Compounds
0
Insecticides
0
Iodobenzenes
0
Metalloporphyrins
0
Triterpenes
0
Manganese
42Z2K6ZL8P
Hydrogen Peroxide
BBX060AN9V
iodosobenzene
TWW7V7Q50P
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2000287Subventions
Organisme : CTQ2015-64049-C3-1-R (MINECO/FEDER)
Informations de copyright
© 2020 Wiley-VHCA AG, Zurich, Switzerland.
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