Large decanuclear calcium and strontium hydride clusters.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
11 Aug 2020
11 Aug 2020
Historique:
pubmed:
14
7
2020
medline:
14
7
2020
entrez:
14
7
2020
Statut:
ppublish
Résumé
Two large decanuclear hydride clusters of the general formula Ae10H16[N(R)R']4·(PMDTA)2 (Ae = Ca, Sr) were isolated. Both derivatives feature a [Ae10H16]4+ core, consisting of two edge shared metal octahedra with interstitial hydrides, while the other hydrides cap triangular faces.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM