Iodine-Transfer Polymerization (ITP) of Ethylene and Copolymerization with Vinyl Acetate.
copolymers
ethylene
iodine transfer polymerization (ITP)
polymerization
vinyl acetate
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
19 Oct 2020
19 Oct 2020
Historique:
received:
25
06
2020
revised:
10
07
2020
pubmed:
16
7
2020
medline:
16
7
2020
entrez:
16
7
2020
Statut:
ppublish
Résumé
Controlled radical polymerization of ethylene using different commercially available, cheap, and non-toxic iodo alkyls is performed by iodine transfer polymerization (ITP) under mild conditions (≤100 °C and ≤200 bar). The formed well-defined iodo end-capped polyethylene (PE-I) species is very stable upon storage. Narrow molar-mass distributions (dispersities around 1.6) were obtained up to number average molar masses of 7300 g mol
Identifiants
pubmed: 32667118
doi: 10.1002/anie.202008872
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
19304-19310Subventions
Organisme : Ministère de l'Enseignement Supérieur, de la Recherche et de l'Innovation
Informations de copyright
© 2020 Wiley-VCH GmbH.
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