Alkylation-Terminated Catellani Reactions Using Alkyl Carbagermatranes.
Catellani reaction
carbagermatranes
ipso-alkylation
main-group chemistry
organogermanium compounds
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
09 Nov 2020
09 Nov 2020
Historique:
received:
15
06
2020
revised:
20
07
2020
pubmed:
22
7
2020
medline:
22
7
2020
entrez:
22
7
2020
Statut:
ppublish
Résumé
The Catellani reaction has received substantial attention because it enables rapid multiple derivatization on aromatics. While using alkyl electrophiles to achieve ortho-alkylation was one of the earliest applications of the Catellani reaction, ipso-alkylation-terminated reactions with β-H-containing reactants has not been realized to date. Herein, we report alkylation-terminated Catellani reaction using alkyl carbagermatranes (abbreviated as alkyl-Ge) as nucleophiles. The reactivity of alkyl-Ge and alkyl-B(OH)
Identifiants
pubmed: 32691946
doi: 10.1002/anie.202008482
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
20450-20454Subventions
Organisme : National Key R&D Program of China
ID : 2017YFA0700104
Organisme : National Natural Science Foundation of China
ID : 21871239
Organisme : Fundamental Research Funds for the Central Universities
ID : WK2060190081
Organisme : Youth Innovation Promotion Association of the Chinese Academy of Sciences
ID : Y201987
Informations de copyright
© 2020 Wiley-VCH GmbH.
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