Photo-releasable derivatives of inositol pyrophosphates.

Cell entry Inositol phosphate Photo-activation Prodrugs Signaling

Journal

Methods in enzymology
ISSN: 1557-7988
Titre abrégé: Methods Enzymol
Pays: United States
ID NLM: 0212271

Informations de publication

Date de publication:
2020
Historique:
entrez: 28 7 2020
pubmed: 28 7 2020
medline: 24 6 2021
Statut: ppublish

Résumé

The specific non-invasive control of intracellular signaling events requires advanced tools that enter cells by diffusion and are controllable by light. Here, we detail the synthesis and application of membrane-permeant caged inositol pyrophosphates with respect to cell entry and cell distribution. We recently published the synthesis of these tools as well as their effect on PH-domain localization in HeLa cells and oscillations of the intracellular calcium concentration in β-cells, which are known to drive insulin secretion. In this chapter, we discuss the possibilities and limitations when using cell-penetrating inositol pyrophosphates. We provide a detailed protocol for the application in live mouse β-cells and we discuss the image analysis needed for following effects on calcium signaling.

Identifiants

pubmed: 32713537
pii: S0076-6879(20)30164-6
doi: 10.1016/bs.mie.2020.04.036
pii:
doi:

Substances chimiques

Diphosphates 0
Inositol Phosphates 0
Calcium SY7Q814VUP

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

53-73

Subventions

Organisme : NIGMS NIH HHS
ID : R01 GM127631
Pays : United States

Informations de copyright

© 2020 Elsevier Inc. All rights reserved.

Auteurs

Sebastian Hauke (S)

European Molecular Biology Laboratory (EMBL), Cell Biology and Biophysics Unit, Heidelberg, Germany.

Tamara Bittner (T)

Institute of Organic Chemistry, University of Freiburg, Freiburg, Germany; CIBSS-Centre for Integrative Biological Signaling Studies, University of Freiburg, Freiburg, Germany.

Henning J Jessen (HJ)

Institute of Organic Chemistry, University of Freiburg, Freiburg, Germany; CIBSS-Centre for Integrative Biological Signaling Studies, University of Freiburg, Freiburg, Germany. Electronic address: henning.jessen@oc.uni-freiburg.de.

Carsten Schultz (C)

Department of Chemical Physiology & Biochemistry, Oregon Health and Science University (OHSU), Portland, OR, United States. Electronic address: schulcar@ohsu.edu.

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Classifications MeSH