Denitrative Cross-Couplings of Nitrostyrenes.

Molecular Structure Nitrates / chemistry Styrenes / chemistry
chalcone conjugated cross-coupling nitrostyrene phosphonate photochemical radical stereoselective stilbene sulfone

Journal

Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009

Informations de publication

Date de publication:
27 Jul 2020
Historique:
received: 24 06 2020
revised: 17 07 2020
accepted: 21 07 2020
entrez: 31 7 2020
pubmed: 31 7 2020
medline: 20 3 2021
Statut: epublish

Résumé

Interestingly, β-nitrostyrenes, typically bench stable compounds, are highly promising cross-coupling partners, due to their excellent availability and well understood reactivity. In this review, we report on the discovery and advancements, in the field of stereoselective, denitrative cross-couplings of β-nitrostyrenes with miscellaneous organic reagents. The rapidly expanding field offers alternative access to a broad range of functionalized alkenes, including β-alkylated styrenes, chalcones, stilbenes, cinnamic acids, and conjugated sulfones and phosphonates. The most important mechanistic pathways are briefly discussed, to familiarize readers with the elementary reactions occurring during the coupling.

Identifiants

DOI: 10.3390/molecules25153390 PMID: 32726964 PMC: PMC7435674
pubmed: 32726964
pii: molecules25153390
doi: 10.3390/molecules25153390
pmc: PMC7435674
pii:
doi:

Substances chimiques

Nitrates 0
Styrenes 0
beta-nitrostyrene 5287E3OUAV

Types de publication

Journal Article Review

Langues

eng

Sous-ensembles de citation

IM

Subventions

Organisme : Agentúra na Podporu Výskumu a Vývoja
ID : APVV-16-0258

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Auteurs

Michaela Marčeková (M)

Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinského 9, 81237 Bratislava, Slovakia.

Branislav Ferko (B)

Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinského 9, 81237 Bratislava, Slovakia.

Katarína Ráchel Detková (KR)

Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinského 9, 81237 Bratislava, Slovakia.

Pavol Jakubec (P)

Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinského 9, 81237 Bratislava, Slovakia.

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Classifications MeSH

questionsmedicales.fr › Phénomènes chimiques › Structure moléculaire › Denitrative Cross-Couplings of Nitrostyrenes.
questionsmedicales.fr › Composés chimiques organiques › Nitrates › Denitrative Cross-Couplings of Nitrostyrenes.
questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures cycliques › Hydrocarbures aromatiques › Dérivés du benzène › Composés benzylidéniques › Styrènes › Denitrative Cross-Couplings of Nitrostyrenes.