Hydrogen Generation from Catalytic Reforming of Paraformaldehyde and Water by Polymeric Bifunctional Catalysts Comprising Ruthenium and Sulfonic Acid Units.


Journal

ChemPlusChem
ISSN: 2192-6506
Titre abrégé: Chempluschem
Pays: Germany
ID NLM: 101580948

Informations de publication

Date de publication:
Aug 2020
Historique:
received: 21 05 2020
revised: 14 07 2020
entrez: 5 8 2020
pubmed: 5 8 2020
medline: 5 8 2020
Statut: ppublish

Résumé

As a clean and sustainable source of energy, hydrogen shows great potential to be the ultimate energy source in future. In this research, paraformaldehyde is used as hydrogen carrier. Several bifunctional catalysts are prepared for the hydrogen generation from paraformaldehyde. The bifunctional catalysts contain two catalytically active sites. One is a sulfonic acid group for paraformaldehyde hydrolysis, and the other is an organometallic group that catalyzes the hydrogen release from formaldehyde. Bifunctional iridium catalysts and bifunctional rhodium catalysts could only generate traces of hydrogen in the initial phase of paraformaldehyde decomposition. Only the bifunctional ruthenium catalyst shows high activity due to its bifunctional catalytically active sites, thus more than 98.0 % of the initially produced gas contains hydrogen. The initial TOF is 685 h

Identifiants

pubmed: 32749755
doi: 10.1002/cplu.202000394
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1646-1654

Subventions

Organisme : National Natural Science Foundation of China
ID : 21902115
Organisme : China Postdoctoral Science Foundation
ID : 2018M632406
Organisme : Ministry of Science and Technology of China
ID : 2016YFE0105700
Organisme : Ministry of Science and Technology of China
ID : 2016YFA0200700

Informations de copyright

© 2020 Wiley-VCH GmbH.

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Auteurs

Yangbin Shen (Y)

Institute of Materials Science and Devices, Suzhou University of Science and Technology, Suzhou, 215009, P. R. China.

Chuang Bai (C)

Division of Advanced Nanomaterials Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, 215123, P. R. China.

Yulu Zhan (Y)

Department of Chemistry Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Laboratory of Advanced Materials, Fudan University, Shanghai, 200433, P. R. China.

Fandi Ning (F)

Division of Advanced Nanomaterials Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, 215123, P. R. China.

Huihui Wang (H)

Division of Advanced Nanomaterials Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, 215123, P. R. China.

Guojun Lv (G)

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, P. R. China.

Xiaochun Zhou (X)

Division of Advanced Nanomaterials Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, 215123, P. R. China.

Classifications MeSH