Novel Low-Temperature Chemical Vapor Deposition of Hydrothermal Delignified Wood for Hydrophobic Property.

As a hydrophilic material, wood is difficult to utilize for external applications due to the variable weather conditions. In this study, an efficient, facile, and low-cost method was developed to enhance the hydrophobicity of wood. By applying the low-temperature chemical vapor deposition (CVD) technology, the polydimethylsiloxane-coated wood (PDMS@wood) with hydrophobic surface was fabricated employing dichlorodimethylsilane as the CVD chemical resource. The result of water contact angle (i.e., 157.3°) revealed the hydrophobic behavior of the PDMS@wood. The microstructures of the wood samples were observed by scanning electron microscopy and energy dispersive X-ray spectroscopy (EDS) analysis verified PDMS successfully coated on wood surfaces. The chemical functional groups of the PDMS@wood were investigated by Fourier transform infrared (FT-IR) and Raman spectra. The thermogravimetric results indicated the enhanced thermal stability of the wood after PDMS coating. In addition, the stability test of PDMS@wood indicated that the hydrophobicity properties of the PDMS@wood samples were preserved after long-time storage (e.g., 30 days). The scratch test was carried out to examine the abrasion resistance of the hydrophobic coatings on PDMS@wood surface. It was suggested that low-temperature CVD process could be a successful approach for fabricating hydrophobic wood.