Tracking Charge Transfer to Residual Metal Clusters in Conjugated Polymers for Photocatalytic Hydrogen Evolution.


Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
26 Aug 2020
Historique:
pubmed: 14 8 2020
medline: 14 8 2020
entrez: 14 8 2020
Statut: ppublish

Résumé

Semiconducting polymers are versatile materials for solar energy conversion and have gained popularity as photocatalysts for sunlight-driven hydrogen production. Organic polymers often contain residual metal impurities such as palladium (Pd) clusters that are formed during the polymerization reaction, and there is increasing evidence for a catalytic role of such metal clusters in polymer photocatalysts. Using transient and operando optical spectroscopy on nanoparticles of F8BT, P3HT, and the dibenzo[

Identifiants

pubmed: 32786800
doi: 10.1021/jacs.0c06104
pmc: PMC7497637
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

14574-14587

Commentaires et corrections

Type : ErratumIn

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Auteurs

Michael Sachs (M)

Department of Chemistry and Centre for Processable Electronics, Imperial College London, 80 Wood Lane, London W12 0BZ, U.K.

Hyojung Cha (H)

Department of Chemistry and Centre for Processable Electronics, Imperial College London, 80 Wood Lane, London W12 0BZ, U.K.

Jan Kosco (J)

Department of Physical Sciences and Engineering, KAUST Solar Centre (KSC) 4700 KAUST, 23955 Thuwal, Saudi Arabia.

Catherine M Aitchison (CM)

Department of Chemistry and Materials Innovation Factory, University of Liverpool, 51 Oxford Street, Liverpool L7 3NY, U.K.

Laia Francàs (L)

Department of Chemistry and Centre for Processable Electronics, Imperial College London, 80 Wood Lane, London W12 0BZ, U.K.

Sacha Corby (S)

Department of Chemistry and Centre for Processable Electronics, Imperial College London, 80 Wood Lane, London W12 0BZ, U.K.

Chao-Lung Chiang (CL)

National Synchrotron Radiation Research Center, 101 Hsin-Ann Road, Hsinchu 30076, Taiwan.

Anna A Wilson (AA)

Department of Chemistry and Centre for Processable Electronics, Imperial College London, 80 Wood Lane, London W12 0BZ, U.K.

Robert Godin (R)

Department of Chemistry and Centre for Processable Electronics, Imperial College London, 80 Wood Lane, London W12 0BZ, U.K.

Alexander Fahey-Williams (A)

Department of Chemistry and Centre for Processable Electronics, Imperial College London, 80 Wood Lane, London W12 0BZ, U.K.

Andrew I Cooper (AI)

Department of Chemistry and Materials Innovation Factory, University of Liverpool, 51 Oxford Street, Liverpool L7 3NY, U.K.

Reiner Sebastian Sprick (RS)

Department of Chemistry and Materials Innovation Factory, University of Liverpool, 51 Oxford Street, Liverpool L7 3NY, U.K.

Iain McCulloch (I)

Department of Physical Sciences and Engineering, KAUST Solar Centre (KSC) 4700 KAUST, 23955 Thuwal, Saudi Arabia.

James R Durrant (JR)

Department of Chemistry and Centre for Processable Electronics, Imperial College London, 80 Wood Lane, London W12 0BZ, U.K.

Classifications MeSH