Unveiling Complexity of the Oxygenation of Aluminum Alkyls by the Isolation of Unique Alkylperoxide and Oxoalkoxide Compounds.
Journal
Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543
Informations de publication
Date de publication:
05 Oct 2020
05 Oct 2020
Historique:
pubmed:
19
8
2020
medline:
19
8
2020
entrez:
19
8
2020
Statut:
ppublish
Résumé
While aluminum alkyls are often considered to be exemplary compounds of main-group organometallics and an in-depth understanding of their multifaceted chemistry is continually vital, the controlled oxygenation of organoaluminum complexes still remains a largely undeveloped area. In the course of our systematic studies on the relationship between the Lewis acidity of metal centers and noncovalent interactions in the secondary coordination sphere, we report the oxygenation of dialkylaluminum complexes incorporating a pyrrole-ester ligand, as purposefully selected dormant Lewis acidic octet-compliant model compounds, and the isolation and characterization of a new, dimeric aluminum
Identifiants
pubmed: 32806017
doi: 10.1021/acs.inorgchem.0c01962
pmc: PMC7539294
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
13807-13811Références
Angew Chem Int Ed Engl. 2012 Apr 23;51(17):4108-11
pubmed: 22419379
Chem Commun (Camb). 2017 Sep 28;53(78):10808-10811
pubmed: 28920981
Inorg Chem. 2005 Mar 7;44(5):1199-201
pubmed: 15732957
Chemistry. 2016 Dec 5;22(49):17776-17783
pubmed: 27786388
Chemistry. 2019 Feb 18;25(10):2503-2510
pubmed: 30516292
Angew Chem Int Ed Engl. 2008;47(41):7888-91
pubmed: 18773401
Chemistry. 2014 Nov 3;20(45):14790-9
pubmed: 25234942
Chemistry. 2000 Sep 1;6(17):3215-27
pubmed: 11002999
Angew Chem Int Ed Engl. 2008;47(3):573-6
pubmed: 18034439
Chem Commun (Camb). 2009 Jan 8;(2):215-7
pubmed: 19099073
Dalton Trans. 2017 Jan 17;46(3):669-677
pubmed: 27966728
J Am Chem Soc. 2012 Aug 8;134(31):13018-26
pubmed: 22839354
Acc Chem Res. 2009 Feb 17;42(2):345-55
pubmed: 19113862
Angew Chem Int Ed Engl. 2019 Nov 25;58(48):17163-17168
pubmed: 31482605
Chemistry. 2011 Feb 1;17(5):1586-95
pubmed: 21268161
Angew Chem Int Ed Engl. 2003 Oct 6;42(38):4643-6
pubmed: 14533152
Chem Commun (Camb). 2002 Aug 7;(15):1586-7
pubmed: 12170794
J Am Chem Soc. 2003 Oct 22;125(42):12698-9
pubmed: 14558804
Chemistry. 2017 Jun 12;23(33):7997-8005
pubmed: 28399333
Chem Commun (Camb). 2016 May 31;52(46):7340-3
pubmed: 27156855
Chemistry. 2008;14(10):3067-71
pubmed: 18283706
PLoS One. 2014 Jun 19;9(6):e100626
pubmed: 24945752
Chem Rev. 1966 Oct;66(5):529-66
pubmed: 5919067
Chem Commun (Camb). 2009 Jan 28;(4):469-70
pubmed: 19137188
Chem Sci. 2015 May 1;6(5):3102-3108
pubmed: 28706684
Angew Chem Int Ed Engl. 2006 Jul 17;45(29):4826-9
pubmed: 16795096
Chem Commun (Camb). 2013 Nov 18;49(89):10477-9
pubmed: 24080918
Angew Chem Int Ed Engl. 2009;48(38):7017-20
pubmed: 19691076
Angew Chem Int Ed Engl. 2019 Jun 17;58(25):8526-8530
pubmed: 30977570
Chemistry. 2003 Oct 6;9(19):4820-8
pubmed: 14566890