Structure and mechanism of B-family DNA polymerase ζ specialized for translesion DNA synthesis.


Journal

Nature structural & molecular biology
ISSN: 1545-9985
Titre abrégé: Nat Struct Mol Biol
Pays: United States
ID NLM: 101186374

Informations de publication

Date de publication:
10 2020
Historique:
received: 23 04 2020
accepted: 29 06 2020
pubmed: 19 8 2020
medline: 18 12 2020
entrez: 19 8 2020
Statut: ppublish

Résumé

DNA polymerase ζ (Polζ) belongs to the same B-family as high-fidelity replicative polymerases, yet is specialized for the extension reaction in translesion DNA synthesis (TLS). Despite its importance in TLS, the structure of Polζ is unknown. We present cryo-EM structures of the Saccharomyces cerevisiae Polζ holoenzyme in the act of DNA synthesis (3.1 Å) and without DNA (4.1 Å). Polζ displays a pentameric ring-like architecture, with catalytic Rev3, accessory Pol31' Pol32 and two Rev7 subunits forming an uninterrupted daisy chain of protein-protein interactions. We also uncover the features that impose high fidelity during the nucleotide-incorporation step and those that accommodate mismatches and lesions during the extension reaction. Collectively, we decrypt the molecular underpinnings of Polζ's role in TLS and provide a framework for new cancer therapeutics.

Identifiants

pubmed: 32807989
doi: 10.1038/s41594-020-0476-7
pii: 10.1038/s41594-020-0476-7
pmc: PMC7554088
mid: NIHMS1608256
doi:

Substances chimiques

Pol32 protein, S cerevisiae 0
REV7 protein, S cerevisiae 0
Saccharomyces cerevisiae Proteins 0
DNA 9007-49-2
DNA polymerase zeta EC 2.7.7.-
DNA Polymerase III EC 2.7.7.7
DNA-Directed DNA Polymerase EC 2.7.7.7
POL31 protein, S cerevisiae EC 2.7.7.7
REV3 protein, S cerevisiae EC 2.7.7.7

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

913-924

Subventions

Organisme : NIGMS NIH HHS
ID : R01 GM124047
Pays : United States
Organisme : NCRR NIH HHS
ID : S10 RR026473
Pays : United States
Organisme : NIGMS NIH HHS
ID : P41 GM103311
Pays : United States
Organisme : NIGMS NIH HHS
ID : P41 GM103310
Pays : United States
Organisme : NCRR NIH HHS
ID : S10 RR029300
Pays : United States
Organisme : NCRR NIH HHS
ID : P41 RR001209
Pays : United States
Organisme : NIH HHS
ID : S10 OD019994
Pays : United States

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Auteurs

Radhika Malik (R)

Department of Pharmacological Sciences, Icahn School of Medicine at Mount Sinai, New York, NY, USA.

Mykhailo Kopylov (M)

Simons Electron Microscopy Center, New York Structural Biology Center, New York, NY, USA.

Yacob Gomez-Llorente (Y)

Department of Pharmacological Sciences, Icahn School of Medicine at Mount Sinai, New York, NY, USA.

Rinku Jain (R)

Department of Pharmacological Sciences, Icahn School of Medicine at Mount Sinai, New York, NY, USA.

Robert E Johnson (RE)

Department of Biochemistry and Molecular Biology, University of Texas Medical Branch, Galveston, TX, USA.

Louise Prakash (L)

Department of Biochemistry and Molecular Biology, University of Texas Medical Branch, Galveston, TX, USA.

Satya Prakash (S)

Department of Biochemistry and Molecular Biology, University of Texas Medical Branch, Galveston, TX, USA.

Iban Ubarretxena-Belandia (I)

Department of Pharmacological Sciences, Icahn School of Medicine at Mount Sinai, New York, NY, USA. iban.ubarretxena@gmail.com.
Instituto Biofisika (UPV/EHU, CSIC), University of the Basque Country, Leioa, Spain. iban.ubarretxena@gmail.com.
Ikerbasque, Basque Foundation for Science, Bilbao, Spain. iban.ubarretxena@gmail.com.

Aneel K Aggarwal (AK)

Department of Pharmacological Sciences, Icahn School of Medicine at Mount Sinai, New York, NY, USA. aneel.aggarwal@mssm.edu.

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