Chlorpyrifos degradation efficiency of

Immobilization Laccase Magnetic nanoparticles Optimization Pesticides

Journal

3 Biotech
ISSN: 2190-572X
Titre abrégé: 3 Biotech
Pays: Germany
ID NLM: 101565857

Informations de publication

Date de publication:
Aug 2020
Historique:
received: 29 01 2020
accepted: 25 07 2020
entrez: 25 8 2020
pubmed: 25 8 2020
medline: 25 8 2020
Statut: ppublish

Résumé

The present study explored the immobilization of laccase onto iron magnetic nanoparticles (MNPs) to enhance its enzymatic properties and applications. The immobilization process was optimized using Box-Behnken design (BBD). BBD showed significance towards the quadratic model with experimental data. Maximum laccase activity recovery (99%) of the predicted model was observed at 0.75 mg/mL of laccase concentration, 200 mg/mL of MNPs, 0.3% cross linking with carbodiimide, and 3 h of cross-linking time. The magnetization activity of MNPs (8 emu/g) and the immobilized laccase with MNPs (4 emu/g) was analyzed using vibrating sample magnetometer (VSM). Maximum activity of immobilized laccase was observed at pH 7.0 and 55 °C. The immobilized laccase has greater stability (100 h) and significant chlorpyrifos (pesticide) degradation activity. High-performance liquid chromatography (HPLC) results confirmed the degraded metabolic products of chlorpyrifos. In all, the immobilized laccase was superior to free laccase, showing promising structural and application characteristics.

Identifiants

pubmed: 32832327
doi: 10.1007/s13205-020-02363-6
pii: 2363
pmc: PMC7394983
doi:

Types de publication

Journal Article

Langues

eng

Pagination

366

Informations de copyright

© King Abdulaziz City for Science and Technology 2020.

Déclaration de conflit d'intérêts

Conflict of interestThe authors declare that they have no conflict of interest.

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Auteurs

P Srinivasan (P)

PG and Research Department of Biotechnology, Mahendra Arts and Science College (Autonomous), Kalippatti, Namakkal, Tamil Nadu 637501 India.

T Selvankumar (T)

PG and Research Department of Biotechnology, Mahendra Arts and Science College (Autonomous), Kalippatti, Namakkal, Tamil Nadu 637501 India.

Bilal Ahamad Paray (BA)

Department of Zoology, College of Science, King Saud University, Riyadh, 11451 Saudi Arabia.

Muneeb U Rehman (MU)

Department of Clinical Pharmacy, College of Pharmacy, King Saud University, Riyadh, 11452 Saudi Arabia.

S Kamala-Kannan (S)

Division of Biotechnology, College of Environmental and Bioresource Sciences, Chonbuk National University, Iksan, 54596 Republic of Korea.

M Govarthanan (M)

Department of Environmental Engineering, Kyungpook National University, Daegu, 41566 Republic of Korea.

Woong Kim (W)

Department of Environmental Engineering, Kyungpook National University, Daegu, 41566 Republic of Korea.

K Selvam (K)

PG and Research Department of Biotechnology, Mahendra Arts and Science College (Autonomous), Kalippatti, Namakkal, Tamil Nadu 637501 India.

Classifications MeSH