Decarboxylative Borylation of Stabilized and Activated Carbon Radicals.

borylation imidoyl chloride inert radicals photoredox reaction

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
01 Dec 2020
Historique:
received: 08 06 2020
revised: 27 07 2020
pubmed: 26 8 2020
medline: 26 8 2020
entrez: 26 8 2020
Statut: ppublish

Résumé

Redox-active esters (RAEs) as active radical precursors have been extensively studied for C-B bond formations. However, the analogous transformations of stabilized radicals from the corresponding acid precursors remain challenging owing to the strong preference towards single-electron oxidation to the stable carbocations. This work describes a general strategy for rapid access to various aliphatic and aromatic boronic esters by mild photoinduced decarboxylative borylation. Both aryl and alkyl radicals could be generated from the leaving group-assisted N-hydroxybenzimidoyl chloride esters, even α-CF

Identifiants

pubmed: 32840957
doi: 10.1002/anie.202008138
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

21875-21879

Subventions

Organisme : National Natural Science Foundation of China
ID : 21772085, 21971107
Organisme : Fundamental Research Funds for the Central Universities
ID : 020514380220, 020514913412, 020514380131
Organisme : National Natural Science Foundation of China
ID : 21772085, 21971107, 22071101

Informations de copyright

© 2020 Wiley-VCH GmbH.

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Auteurs

Qiang Zhang (Q)

State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.

Xiaojuan Li (X)

State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.

Weigang Zhang (W)

State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.

Shengyang Ni (S)

State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.

Yi Wang (Y)

State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.

Yi Pan (Y)

State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.

Classifications MeSH