Selective Hydroperoxygenation of Olefins Realized by a Coinage Multimetallic 1-Nanometer Catalyst.
dendrimers
metal-metal interactions
nanoparticles
peroxides
supported catalysts
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
14 Dec 2020
14 Dec 2020
Historique:
received:
25
07
2020
pubmed:
28
8
2020
medline:
28
8
2020
entrez:
27
8
2020
Statut:
ppublish
Résumé
The science of particles on a sub-nanometer (ca. 1 nm) scale has attracted worldwide attention. However, it has remained unexplored because of the technical difficulty in the precise synthesis of sub-nanoparticles (SNPs). We recently developed the "atom-hybridization method (AHM)" for the precise synthesis of SNPs by using a suitably designed macromolecule as a template. We have now investigated the chemical reactivity of alloy SNPs obtained by the AHM. Focusing on the coinage metal elements, we systematically evaluated the oxidation reaction of an olefin catalyzed by these SNPs. The SNPs showed high catalytic performance even under milder conditions than those used with conventional catalysts. Additionally, the hybridization of multiple elements enhanced the turnover frequency and the selectivity for the formation of the hydroperoxide derivative. We discuss the unique quantum-sized catalysts providing generally unstable hydroperoxides from the viewpoint of the miniaturization and hybridization of materials.
Identifiants
pubmed: 32844511
doi: 10.1002/anie.202010190
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
23051-23055Subventions
Organisme : Japan Science and Technology Agency
ID : JPMJER1503
Organisme : JSPS KAKENHI
ID : JP19K15583
Organisme : Tokyo Institute of Technology
ID : Yoshinori Ohsumi Fund for Fundamental Research
Organisme : JSPS KAKENHI
ID : JP15H05757
Organisme : Advanced Technology Institute
ID : a research grant from the Advanced Technology Institute
Informations de copyright
© 2020 Wiley-VCH GmbH.
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