Vivid Wording for the Chemistry of Group 4 Metallocene Complexes.
Group 4 metals
coordination chemistry
organometallics chemistry
terminology
unusual reactions
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
02 Nov 2020
02 Nov 2020
Historique:
received:
14
05
2020
pubmed:
31
8
2020
medline:
31
8
2020
entrez:
1
9
2020
Statut:
ppublish
Résumé
Three selected examples for the use of unusual wording to describe the organometallic chemistry of Group 4 metallocenes are explained and discussed. The term "tuck(ed)-in" concerns the behavior of decamethyltitanocene [(C
Identifiants
pubmed: 32864835
doi: 10.1002/anie.202006969
doi:
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
19756-19761Informations de copyright
© 2020 Wiley-VCH GmbH.
Références
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J. A. Smith, H. H. Brintzinger, J. Organomet. Chem. 1981, 218, 159-167;
H. H. Brintzinger, D. Fischer, R. Mülhaupt, B. Rieger, R. M. Waymouth, Angew. Chem. Int. Ed. Engl. 1995, 34, 1143-1170;
Angew. Chem. 1995, 107, 1255-1283, and refs. cited therein.
“ansa”:
A. Lüttringhaus, Habilitation at the University of Heidelberg, 1937;
H. Prinzbach, Eur. J. Org. Chem. 1998, 735-743, and refs. cited therein.
“Tuck(ed) in”:
F. G. N. Cloke, J. C. Green, M. L. H. Green, C. P. Morley, J. Chem. Soc. Chem. Commun. 1985, 945-946;
J. W. Pattiasina, F. van Bolhuis, J. H. Teuben, Angew. Chem. Int. Ed. Engl. 1987, 26, 330-331;
Angew. Chem. 1987, 99, 342-343;
J. E. Bercaw, J. Am. Chem. Soc. 1974, 96, 5087-5095;
J. E. Bercaw, R. H. Marvich, L. G. Bell, H. H. Brintzinger, J. Am. Chem. Soc. 1972, 94, 1219;
J. E. Bercaw, H. H. Brintzinger, J. Am. Chem. Soc. 1971, 93, 2048;
J. C. McDade, J. C. Green, J. E. Bercaw, Organometallics 1982, 1, 1629;
G. A. Luinstra, J. H. Teuben, J. Am. Chem. Soc. 1992, 114, 3361;
G. A. Luinstra, L. C. ten Cate, H. J. Heeres, J. W. Pattiasina, A. Meetsma, J. H. Teuben, Organometallics 1991, 10, 2665;
J. M. Fischer, W. E. Piers, V. G. Young, Organometallics 1996, 15, 2410;
J. W. Pattiasina, C. E. Hissink, J. L. deBoer, A. Meetsma, J. H. Teuben, A. L. Spek, J. Am. Chem. Soc. 1985, 107, 7758;
R. Fandos, A. Meetsma, J. H. Teuben, Organometallics 1991, 10, 2665;
R. Beckhaus, J. Sang, J. Oster, T. Wagner, J. Organomet. Chem. 1994, 484, 179;
S. I. Troyanov, K. Mach, V. Varga, Organometallics 1993, 12, 3387;
V. Varga, K. Mach, M. Polasek, P. Sedmera, J. Hiller, U. Thewalt, S. I. Troyanov, J. Organomet. Chem. 1996, 506, 241.
“Tuck(ed) in” reactions for two Me groups and 1,3-butadiynes:
P.-M. Pellny, F. G. Kirchbauer, V. V. Burlakov, W. Baumann, A. Spannenberg, U. Rosenthal, Chem. Eur. J. 2000, 6, 81-90;
U. Rosenthal, P.-M. Pellny, F. G. Kirchbauer, V. V. Burlakov, Acc. Chem. Res. 2000, 33, 119-129;
M. Horáček, I. Císařová, J. Kubišta, A. Spannenberg, K. Dallmann, U. Rosenthal, K. Mach, J. Organomet. Chem. 2004, 689, 4592-4600;
P.-M. Pellny, V. V. Burlakov, W. Baumann, A. Spannenberg, M. Horacek, P. Stepnicka, K. Mach, U. Rosenthal, Organometallics 2000, 19, 2816-2819;
M. Horáček, P. Štěpnička, R. Gyepes, I. Císařová, M. Polášek, K. Mach, P.-M. Pellny, V. V. Burlakov, W. Baumann, A. Spannenberg, U. Rosenthal, J. Am. Chem. Soc. 1999, 121, 10638-10639.
Selected examples for titanium:
J. Pinkas, K. Mach, J. Kubista, M. Horacek, K. Szarka, R. Gyepes, J. Mol. Struct. 2018, 1167, 180-186;
M. Horáček, I. Císařová, R. Gyepes, J. Kubišta, J. Pinkas, M. Lamač, K. Mach, J. Organomet. Chem. 2014, 755, 141-150;
J. Pinkas, I. Cisarova, R. Gyepes, J. Kubista, M. Horacek, K. Mach, Organometallics 2012, 31, 5478-5493;
J. Pinkas, I. Cisarova, M. Horacek, J. Kubista, K. Mach, Organometallics 2011, 30, 1034-1045;
M. Horáček, R. Gyepes, I. Císařová, J. Kubišta, J. Pinkas, K. Mach, J. Organomet. Chem. 2010, 695, 2338-2344;
R. Gyepes, V. Varga, M. Horacek, J. Kubista, J. Pinkas, K. Mach, Organometallics 2010, 29, 3780-3789;
J. Pinkas, I. Cisarova, A. Conde, R. Fandos, M. Horacek, J. Kubista, K. Mach, J. Organomet. Chem. 2009, 694, 1971-1980;
V. Varga, I. Cisarova, M. Horacek, J. Pinkas, J. Kubista, K. Mach, Collect. Czech. Chem. Commun. 2009, 74, 453-468,
V. Varga, I. Cisarova, R. Gyepes, M. Horacek, J. Kubista, K. Mach, Organometallics 2009, 28, 1748-1757;
J. Pinkas, I. Cisarova, A. Conde, R. Fandos, M. Horacek, J. Kubista, K. Mach, Inorg. Chem. Commun. 2009, 12, 11-14;
J. Pinkas, I. Cisarova, R. Gyepes, M. Horacek, J. Kubista, J. Cejka, S. Gomez-Ruiz, E. Hey-Hawkins, K. Mach, Organometallics 2008, 27, 5532-5547;
J. Pinkas, L. Lukesova, R. Gyepes, I. Cisarova, P. Lönnecke, J. Kubista, M. Horacek, K. Mach, Organometallics 2007, 26, 3100-3110;
V. Varga, P. Sindelar, I. Cisarova, M. Horacek, J. Kubista, K. Mach, Inorg. Chem. Commun. 2005, 8, 222-226;
M. Horáček, R. Gyepes, J. Kubišta, K. Mach, Inorg. Chem. Commun. 2004, 7, 155-159;
S. Fox, J. P. Dunne, M. Tacke, J. F. Gallagher, Inorg. Chim. Acta 2004, 357, 225-234;
H. van der Heijden, B. Hessen, Inorg. Chim. Acta 2003, 345, 27-36;
M. Horacek, P. Stepnicka, J. Kubista, I. Cisarova, L. Petrusova, K. Mach, J. Organomet. Chem. 2003, 667, 154-166;
M. Horacek, P. Stepnicka, J. Kubista, R. Gyepes, I. Cisarova, L. Petrusova, K. Mach, J. Organomet. Chem. 2002, 658, 235-241;
F. T. Edelmann, S. Giessmann, A. Fischer, J. Organomet. Chem. 2001, 620, 80-89;
V. Kupfer, U. Thewalt, I. Tislerova, P. Stepnicka, R. Gyepes, J. Kubista, M. Horacek, K. Mach, J. Organomet. Chem. 2001, 620, 39-50;
V. Kupfer, U. Thewalt, M. Horacek, L. Petrusova, K. Mach, Inorg. Chem. Commun. 1999, 2, 540-544;
E. Novarino, I. Guerrero Rios, S. van der Veer, A. Meetsma, B. Hessen, M. W. Bouwkamp, Organometallics 2011, 30, 92-99.
Selected examples for zirconium:
O. Àrias, A. R. Petrov, T. Bannenberg, K. Altenburger, P. Arndt, P. G. Jones, U. Rosenthal, M. Tamm, Organometallics 2014, 33, 1774-1786;
J. A. Pool, C. A. Bradley, P. J. Chirik, Organometallics 2002, 21, 1271-1277;
Y. Sun, R. E. v. H. Spence, W. E. Piers, M. Parvez, G. P. A. Yap, J. Am. Chem. Soc. 1997, 119, 5132-5143.
C−C bond cleavage of Cp and additional intramolecular C−C coupling: A. Tillack, W. Baumann, A. Ohff, C. Lefeber, A. Spannenberg, U. Rosenthal, J. Organomet. Chem. 1996, 520, 187-193.
“Merry-go-round reaction”:
M. Bando, K. Nakajima, Z. Song, T. Takahashi, Organometallics 2019, 38, 731-734;
Z. Xi, K. Sato, Y. Gao, J. Lu, T. Takahashi, J. Am. Chem. Soc. 2003, 125, 9568-9569;
T. Takahashi, Y. Kuzuba, F. Kong, K. Nakajima, Z. Xi, J. Am. Chem. Soc. 2005, 127, 17181-17189;
T. Takahashi, Z. Song, K. Sato, Y. Kuzuba, K. Nakajima, K. Kanno, J. Am. Chem. Soc. 2007, 129, 11678-11679;
T. Takahashi, Z. Song, Y.-F. Hsieh, K. Nakajima, K. Kanno, J. Am. Chem. Soc. 2008, 130, 15236-15237;
Y. Mizukami, H. Li, K. Nakajima, Z. Song, T. Takahashi, Angew. Chem. Int. Ed. 2014, 53, 8899-8903;
Angew. Chem. 2014, 126, 9045-9049;
Z. Song, Y.-F. Hsieh, K. Nakajima, K. Kanno, T. Takahashi, Organometallics 2016, 35, 1092-1097;
M. Bando, Y. Mizukami, K. Nakajima, Z. Song, T. Takahashi, Dalton Trans. 2017, 46, 16408-16411.
“Sliding”, “migration”, or “tobogganing” of metallocenes: P. M. Pellny, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, J. Am. Chem. Soc. 2000, 122, 6317-6318.
Linear polyynes: P. M. Pellny, N. Peulecke, V. V. Burlakov, A. Tillack, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, Angew. Chem. Int. Ed. Engl. 1997, 36, 2615-2617;
Angew. Chem. 1997, 109, 2728-2730.
Branched polyynes: P. M. Pellny, V. V. Burlakov, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, Organometallics 1999, 18, 2906-2909.
Vanadocene:
C. Danjoy, J. Zhao, B. Donnadieu, J.-P. Legros, L. Valade, R. Choukroun, A. Zwick, P. Cassoux, Chem. Eur. J. 1998, 4, 1100-1105;
R. Choukroun, P. Cassoux, Acc. Chem. Res. 1999, 32, 494-502;
R. Choukroun, C. Lorber, B. Donnadieu, B. Henner, R. Frantz, C. Guerin, Chem. Commun. 1999, 1099-1100;
R. Choukroun, B. Donnadieu, C. Lorber, P.-M. Pellny, W. Baumann, U. Rosenthal, Chem. Eur. J. 2000, 6, 4505-4509.
Ditungsten ethanediylidyne: B. J. Frogley, A. F. Hill, Angew. Chem. Int. Ed. 2019, 58, 8044-8048;
Angew. Chem. 2019, 131, 8128-8132.