Luminescent tungsten(vi) complexes as photocatalysts for light-driven C-C and C-B bond formation reactions.
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
07 Jul 2020
07 Jul 2020
Historique:
received:
05
03
2020
accepted:
23
05
2020
entrez:
3
9
2020
pubmed:
3
9
2020
medline:
3
9
2020
Statut:
epublish
Résumé
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(vi) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
Identifiants
pubmed: 32874518
doi: 10.1039/d0sc01340d
pii: d0sc01340d
pmc: PMC7448528
doi:
Types de publication
Journal Article
Langues
eng
Pagination
6370-6382Informations de copyright
This journal is © The Royal Society of Chemistry 2020.
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