Reconstruction-Determined Alkaline Water Electrolysis at Industrial Temperatures.

alkaline water electrolysis complete reconstruction grain/phase boundaries in situ low-/high-temperature Raman industrial temperatures, nanowire arrays

Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Oct 2020
Historique:
received: 17 02 2020
revised: 06 08 2020
pubmed: 3 9 2020
medline: 3 9 2020
entrez: 3 9 2020
Statut: ppublish

Résumé

Evaluating the alkaline water electrolysis (AWE) at 50-80 °C required in industry can veritably promote practical applications. Here, the thermally induced complete reconstruction (TICR) of molybdate oxygen evolution reaction (OER) pre-catalysts at 51.9 °C and its fundamental mechanism are uncovered. The dynamic reconstruction processes, the real active species, and stereoscopic structural characteristics are identified by in situ low-/high-temperature Raman, ex situ microscopy, and electron tomography. The completely reconstructed (CR) catalyst (denoted as cat.-51.9) is interconnected by thermodynamically stable (oxy)hydroxide nanoparticles, with abundant boundaries and low crystallinity. For alkaline OER, cat.-51.9 exhibits a low overpotential (282.3 mV at 20 mA cm

Identifiants

pubmed: 32876959
doi: 10.1002/adma.202001136
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2001136

Subventions

Organisme : National Natural Science Foundation of China
ID : 51521001
Organisme : National Natural Science Foundation of China
ID : 21890751
Organisme : Advanced Energy Science and Technology Guangdong Laboratory
ID : XHT2020-003
Organisme : China Postdoctoral Science Foundation
ID : 2019TQ0306
Organisme : National Key Research and Development Program of China
ID : 2016YFA0202603

Informations de copyright

© 2020 Wiley-VCH GmbH.

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Auteurs

Xiong Liu (X)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.

Ruiting Guo (R)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.

Kun Ni (K)

Hefei National Laboratory for Physical Sciences at the Microscale, School of Chemistry and Materials Sciences, CAS Key Laboratory of Materials for Energy Conversion, CAS Center for Excellence in Nanoscience, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), University of Science and Technology of China, Hefei, Anhui, 230026, China.

Fanjie Xia (F)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.

Chaojiang Niu (C)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.

Bo Wen (B)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.

Jiashen Meng (J)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.

Peijie Wu (P)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.

Jinsong Wu (J)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.

Xiaojun Wu (X)

Hefei National Laboratory for Physical Sciences at the Microscale, School of Chemistry and Materials Sciences, CAS Key Laboratory of Materials for Energy Conversion, CAS Center for Excellence in Nanoscience, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), University of Science and Technology of China, Hefei, Anhui, 230026, China.

Liqiang Mai (L)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.
Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Xianhu hydrogen Valley, Foshan, 528200, China.

Classifications MeSH