Conjugated Nanohoops Incorporating Donor, Acceptor, Hetero- or Polycyclic Aromatics.

cyclacenes cycloparaphenylenes macrocycles nanohoops optoelectronic properties

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
12 Jul 2021
Historique:
revised: 05 08 2020
received: 15 05 2020
pubmed: 10 9 2020
medline: 10 9 2020
entrez: 9 9 2020
Statut: ppublish

Résumé

In the last 13 years several synthetic strategies were developed that provide access to [n]cycloparaphenylenes ([n]CPPs) and related conjugated nanohoops. A number of potential applications emerged, including optoelectronic devices, and their use as templates for carbon nanomaterials and in supramolecular chemistry. To tune the structural or optoelectronic properties of carbon nanohoops beyond the size-dependent effect known for [n]CPPs, a variety of aromatic rings other than benzene were introduced. In this Review, we provide an overview of the syntheses, properties, and applications of conjugated nanohoops beyond [n]CPPs with intrinsic donor/acceptor structure or such that contain acceptor, donor, heteroaromatic or polycyclic aromatic units within the hoop as well as conjugated nanobelts.

Identifiants

pubmed: 32902109
doi: 10.1002/anie.202007024
pmc: PMC9542246
doi:

Types de publication

Journal Article Review

Langues

eng

Sous-ensembles de citation

IM

Pagination

15743-15766

Subventions

Organisme : Deutsche Forschungsgemeinschaft
ID : 230408635
Organisme : Deutsche Forschungsgemeinschaft
ID : 434040413

Informations de copyright

© 2020 The Authors. Published by Wiley-VCH GmbH.

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Auteurs

Mathias Hermann (M)

Institute for Organic Chemistry, University of Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

Daniel Wassy (D)

Institute for Organic Chemistry, University of Freiburg, Albertstr. 21, 79104, Freiburg, Germany.

Birgit Esser (B)

Institute for Organic Chemistry, University of Freiburg, Albertstr. 21, 79104, Freiburg, Germany.
Freiburg Materials Research Center, University of Freiburg, Stefan-Meier-Str. 21, 79104, Freiburg, Germany.
Freiburg Center for Interactive Materials and Bioinspired Technologies, University of Freiburg, Georges-Köhler-Allee 105, 79110, Freiburg, Germany.

Classifications MeSH