Enantiomeric Excess Dependent Splitting of NMR Signal through Dynamic Chiral Inversion and Coligand Exchange in a Coordination Complex.

Journal

The journal of physical chemistry letters
ISSN: 1948-7185
Titre abrégé: J Phys Chem Lett
Pays: United States
ID NLM: 101526034

Informations de publication

Date de publication:
01 Oct 2020
Historique:
pubmed: 10 9 2020
medline: 10 9 2020
entrez: 9 9 2020
Statut: ppublish

Résumé

Nuclear magnetic resonance (NMR) spectroscopy cannot be used to discriminate enantiomers, and NMR resonances of enantiomeric mixtures are generally not affected by enantiomeric excess (

Identifiants

DOI: 10.1021/acs.jpclett.0c02284 PMID: 32902288
pubmed: 32902288
doi: 10.1021/acs.jpclett.0c02284
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

8164-8169

Auteurs

Kazuyoshi Takimoto (K)

Graduate School of Science and Engineering, Ehime University, Matsuyama, Ehime 790-8577, Japan.
International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.
ORCID: 0000-0002-2969-6297

Shinsuke Ishihara (S)

International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.
ORCID: 0000-0001-6854-6032

Jan Labuta (J)

International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.
ORCID: 0000-0002-8329-0634

Václav Březina (V)

Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 180 00 Prague 8, Czech Republic.
ORCID: 0000-0001-5772-7006

Daniel T Payne (DT)

International Center for Young Scientists (ICYS), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.
ORCID: 0000-0001-7707-8381

Jonathan P Hill (JP)

International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.
ORCID: 0000-0002-4229-5842

Katsuhiko Ariga (K)

International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.
Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, Kashiwa, Chiba 277-8561, Japan.
ORCID: 0000-0002-2445-2955

Masato Sumita (M)

International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.
Center for Advanced Intelligence Project, RIKEN, Chuo-ku, Tokyo 103-0027, Japan.
ORCID: 0000-0002-3506-1028

Shigeki Mori (S)

Advanced Research Support Center, Ehime University, Matsuyama, Ehime 790-8577, Japan.
ORCID: 0000-0001-6731-2357

Hisako Sato (H)

Graduate School of Science and Engineering, Ehime University, Matsuyama, Ehime 790-8577, Japan.
ORCID: 0000-0002-3927-1794

Classifications MeSH