Achieving Purely-Organic Room-Temperature Aqueous Phosphorescence via a Two-Component Macromolecular Self-Assembly Strategy.
aggregation
block copolymers
nanostructures
phosphorescence
self-assembly
Journal
Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643
Informations de publication
Date de publication:
02 Nov 2020
02 Nov 2020
Historique:
received:
14
08
2020
revised:
07
09
2020
pubmed:
11
9
2020
medline:
11
9
2020
entrez:
10
9
2020
Statut:
ppublish
Résumé
Manipulation of supramolecular behaviors and aggregation states represents an important topic in devising intriguing photofunctional systems. Here we report a two-component macromolecular self-assembly strategy for achieving aqueous room-temperature phosphorescence (RTP) in purely organic systems. Amphiphilic triblock copolymers are used to modulate the self-assembly of planar RTP molecules in aqueous solution, leading to the formation of sheet-like RTP objects with well-defined morphology, uniform crystalline nanostructures and excellent aqueous dispersity. In contrast, the addition of the planar RTP molecules into aqueous medium only leads to precipitation and quenching of RTP properties. Powder X-ray diffraction and single-crystal X-ray diffraction studies reveal that the amphiphilic triblock copolymers can assist supramolecular columnar packing of the planar RTP molecules where multiple non-covalent interactions stabilize the triplet excited states. Interestingly, it is found that luminescent signals of the sheet-like RTP objects can be extracted from strong fluorescent environments by phosphorescence mode and emission lifetime measurement.
Identifiants
pubmed: 32909394
doi: 10.1002/asia.202000965
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
3469-3474Subventions
Organisme : Shanghai Scientific and Technological Innovation Project
ID : 20QA1411600
Organisme : Shanghai Scientific and Technological Innovation Project
ID : 20ZR1469200
Organisme : Hundred Talents Program from Shanghai Institute of Organic Chemistry
ID : Y121078
Organisme : National Facility for Protein Science (NFPS)
Organisme : Shanghai Synchrotron Radiation Facility (SSRF)
Informations de copyright
© 2020 Wiley-VCH GmbH.
Références
V. W.-W. Yam, V. K.-M. Au, S. Y.-L. Leung, Chem. Rev. 2015, 115, 7589.
J. Mei, N. L.-C. Leung, R. T.-K. Kwok, J. W.-Y. Lam, B. Z. Tang, Chem. Rev. 2015, 115, 11718.
D. Chen, M. Jiang, Acc. Chem. Res. 2005, 38,494.
M. Guo, M. Jiang, Soft Matter 2009, 5, 495.
K. Zhang, S. Y.-L. Yeung, S. Y.-L. Leung, V. W.-W. Yam, Chem 2017, 2, 825.
A. F. Thünemann, S. Kubowicz, C. Burger, M. D. Watson, N. Tchebotareva, K. Müllen, J. Am. Chem. Soc. 2003, 125, 352.
K. Zhang, S. Y.-L. Yeung, S. Y.-L. Leung, V. W.-W. Yam, Proc. Natl. Acad. Sci. USA, 2017, 114, 11844.
M. Huang, U. Schilde, M. Kumke, M. Antonietti, H. Cölfen, J. Am. Chem. Soc. 2010, 132, 3700.
K. Zhang, S. Y.-L. Yeung, S. Y.-L. Leung, V. W.-W. Yam, J. Am. Chem. Soc. 2018, 140, 9594.
G. Zhang, J. Chen, S. J. Payne, S. E. Kooi, J. N. Demas, C. L. Fraser, J. Am. Chem. Soc. 2007, 129, 8942.
W. Z. Yuan, X. Y. Shen, H. Zhao, J. W. Y. Lam, L. Tang, P. Lu, C. Wang, Y. Liu, Z. Wang, Q. Zheng, J. Z. Sun, Y. Ma, B. Z. Tang, J. Phys. Chem. C 2010, 114, 6090.
J. Wang, X. Gu, H. Ma, Q. Peng, X. Huang, X. Zheng, S. H.-P. Sung, G. Shan, J. W.-Y. Lam, Z. Shuai, B. Z. Tang, Nat. Commun. 2018, 9, 2963.
O. Bolton, K. Lee, H. J. Kim, K. Y. Lin, J. Kim, Nat. Chem. 2011, 3, 205.
Z. An, C. Zheng, Y. Tao, R. Chen, H. Shi, T. Chen, Z. Wang, H. Li, R. Deng, X. Liu, W. Huang, Nat. Mater. 2015, 14, 685.
S. Hirata, K. Totani, J. Zhang, T. Yamashita, H. Kaji, S. R. Marder, T. Watanabe, C. Adachi, Adv. Funct. Mater. 2013, 23, 3386.
G. Zhang, G. M. Palmer, M. W. Dewhirst, C. L. Fraser, Nat. Mater. 2009, 8, 747.
Y. Yu, M. S. Kwon, J. Jung, Y. Zeng, M. Kim, K. Chung, J. Gierschner, J. H. Youk, S. M. Borisov, J. Kim, Angew. Chem. Int. Ed. 2017, 56, 16207.
J. Zhao, Z. He, J. W. Y. Chan, Q. Peng, H. Ma, Z. Shuai, G. Bai, J. Hao, B. Z. Tang, Chem 2016, 1, 592.
J. Wei, B. Liang, R. Duan, Z. Cheng, C. Li, T. Zhou, Y. Yi, Y. Wang, Angew. Chem. Int. Ed. 2016, 55, 15589.
J. Jin, H. Jiang, Q. Yang, L. Tang, Y. Tao, Y. Li, R. Chen, C. Zheng, Q. Fan, K. Y. Zhang, Q. Zhao, W. Huang, Nat. Commun. 2020, 11, 842.
X. F. Wang, H. Xiao, P. Z. Chen, Q. Z. Yang, B. Chen, C. H. Tung, Y. Z. Chen, L. Z. Wu, J. Am. Chem. Soc. 2019, 141, 5045.
X. Zhen, Y. Tao, Z. An, P. Chen, C. Xu, R. Chen, W. Huang, K. Pu, Adv. Mater. 2017, 29, 1606665.
Z. He, H. Gao, S. Zhang, S. Zheng, Y. Wang, Z. Zhao, D. Ding, B. Yang, Y. Zhang, W. Z. Yuan, Adv. Mater. 2019, 31, 1807222.
Y. You, K. Huang, X. Liu, X. Pan, J. Zhi, Q. He, H. Shi, Z. An, X. Ma, W. Huang, Small 2020, 16, 1906733.
J. Yang, X. Zhen, B. Wang, X. Gao, Z. Ren, J. Wang, Y. Xie, J. Li, Q. Peng, K. Pu, Z. Li, Nat. Commun. 2018, 9, 840.
H. Shi, L. Zou, K. Huang, H. Wang, C. Sun, S. Wang, H. Ma, Y. He, J. Wang, H. Yu, W. Yao, Z. An, Q. Zhao, W. Huang, ACS Appl. Mater. Interfaces 2019, 11, 18103.
Y. Gong, G. Chen, Q. Peng, W. Z. Yuan, J. Xie, S. Li, Y. Zhang, B. Z. Tang, Adv. Mater. 2015, 27, 6195.
Z. Mao, Z. Yang, Y. Mu, Y. Zhang, Y. F. Wang, Z. Chi, C. C. Lo, S. Liu, A. Lien, J. Xu, Angew. Chem. Int. Ed. 2015, 54, 6270.
S. Cai, H. Shi, J. Li, L. Gu, Y. Ni, Z. Cheng, S. Wang, W. W. Xiong, L. Li, Z. An, W. Huang, Adv. Mater. 2017, 29, 1701244.
Y. Xie, Y. Ge, Q. Peng, C. Li, Q. Li, Z. Li, Adv. Mater. 2017, 29, 1606829.
N. Gan, X. Wang, H. Ma, A. Lv, H. Wang, Q. Wang, M. Gu, S. Cai, Y. Zhang, L. Fu, M. Zhang, C. Dong, W. Yao, H. Shi, Z. An, W. Huang, Angew. Chem. Int. Ed. 2019, 58, 14140.
H. Wu, W. Chi, Z. Chen, G. Liu, L. Gu, A. K. Bindra, G. Yang, X. Liu, Y. Zhao, Adv. Funct. Mater. 2019, 29, 1807243.
C. Chen, R. Huang, A. S. Batsanov, P. Pander, Y. T. Hsu, Z. Chi, F. B. Dias, M. R. Bryce, Angew. Chem. Int. Ed. 2018, 57, 16407.
H. Ma, Q. Peng, Z. An, W. Huang, Z. Shuai, J. Am. Chem. Soc. 2019, 141, 1010.
H. Wu, Y. Zhou, L. Yin, C. Hang, X. Li, H. Ågren, T. Yi, Q. Zhang, L. Zhu, J. Am. Chem. Soc. 2017, 139, 785.
X. Ma, C. Xu, J. Wang, H. Tian, Angew. Chem. Int. Ed. 2018, 57, 10854.
S. Cai, H. Ma, H. Shi, H. Wang, X. Wang, L. Xiao, W. Ye, K. Huang, X. Cao, N. Gan, C. Ma, M. Gu, L. Song, H. Xu, Y. Tao, C. Zhang, W. Yao, Z. An, W. Huang, Nat. Commun. 2019, 10, 4247.
D. Li, F. Lu, J. Wang, W. Hu, X. M. Cao, X. Ma, H. Tian, J. Am. Chem. Soc. 2018, 140, 1916.
Z. Y. Zhang, Y. Chen, Y. Liu, Angew. Chem. Int. Ed. 2019, 58, 6028.
T. Watanabe, S. Ueda, S. Inuki, S. Oishi, N. Fujii, H. Ohno, Chem. Commun. 2007, 43, 4516.
L.-F. Yu, C.-W. Ge, J.-T. Wang, X. Xiang, W.-S. Li, Polymer 2015, 59, 57.
K. Jankova, X. Chen, J. Kops, W. Batsberg, Macromolecules 1998, 31, 538.
K. A. Davis, K. Matyjaszewski, Macromolecules 2000, 33, 4039.
S. N. Sidorov, L. M. Bronstein, Y. A. Kabachii, P. M. Valetsky, P. L. Soo, D. Maysinger, A. Eisenberg, Langmuir 2004, 20, 3543.
J. Xia, X. Zhang, K. Matyjaszewski, Macromolecules 1999, 32, 3531.