The impact of non-thermal plasma on the adhesion of polyetherketoneketone (PEKK) to a veneering composite system.

The PEKK material can be used in prosthodontics for framework manufacturing and is commonly laminated with veneering composites to achieve a better esthetics. Various surface treatment methods including sandblasting, etching, laser and cold plasma treatments were reported to enhance the adhesive properties of dental polymers. Both tensile and shear bond test were employed to quantify the bond strength between PEKK and veneering composites. The present in vitro study aims to evaluate the influence of acetylene, argon, air, nitrogen and oxygen plasma on the shear bond strength between PEKK and one veneering composite. Firstly, to determine which bond test type should be applied, n = 40 PEKK specimens were treated with argon plasma. Both shear and tensile bond tests were performed and compared to the control group (n = 40). In shear bond testing, values were 8.14 ± 1.70 MPa for Argon plasma while 5.83 ± 1.42 MPa for control group. In tensile bond testing, Argon plasma 1.50 ± 0.51 MPa while control group 0.58 ± 0.50 MPa. Afterwards n = 160 PEKK specimens were treated with rocatec sandblasting (n = 20), adhesive (n = 20), acetylene (n = 20), argon (n = 20), air (n = 20), nitrogen (n = 20), oxygen (n = 20) plasma types and compared to the untreated control group (n = 20) using shear bond strength test (SBS). Additionally surface roughness and scanning electron microscopy analyses were performed. The following SBS values were revealed: 10.22 ± 1.06 MPa for rocatec; 9.89 ± 3.08 MPa for acetylene, 9.16 ± 1.48 MPa for adhesive, 7.54 ± 1.52 MPa for argon, 7.09 ± 1.99 MPa for air, 7.03 ± 1.48 MPa for nitrogen, 5.69 ± 1.59 MPa for oxygen plasma types and 4.71 ± 1.54 MPa for the control group. All groups, except control group, showed SBS over 5 MPa, which means that they are suitable for the clinical application, according to ISO 10477. Acetylene showed the highest SBS among all plasma types (p < 0.0001), which was on a level of rocatec sandblasting group. Rocatec and acetylene groups demonstrated Ra values significantly different to the reference group (p < 0.0001). Plasma treatment especially with acetylene gas can be an effective more convenient surface treatment method for strengthening the bond strength between PEKK and veneering composites than traditional sandblasting/adhesive treatment.

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