Quantum-State Controlled Reaction Channels in Chemi-ionization Processes: Radiative (Optical-Physical) and Exchange (Oxidative-Chemical) Mechanisms.
Journal
Accounts of chemical research
ISSN: 1520-4898
Titre abrégé: Acc Chem Res
Pays: United States
ID NLM: 0157313
Informations de publication
Date de publication:
20 Oct 2020
20 Oct 2020
Historique:
pubmed:
16
9
2020
medline:
16
9
2020
entrez:
15
9
2020
Statut:
ppublish
Résumé
ConspectusMost chemical processes are triggered by electron or charge transfer phenomena (CT). An important class of processes involving CT are chemi-ionization reactions. Such processes are very common in nature, involving neutral species in ground or excited electronic states with sufficient energy (X*) to yield ionic products, and are considered as the primary initial step in flames. They are characterized by pronounced electronic rearrangements that take place within the collisional complex (X···M)* formed by approaching reagents, as shown by the following scheme, where M is an atomic or molecular target: X* + M → (X···M)* → [(X
Identifiants
pubmed: 32930573
doi: 10.1021/acs.accounts.0c00371
pmc: PMC8011800
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
2248-2260Références
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